ArticleChemical science2019
The acidic nature of "NMR-invisible" tri-coordinated framework aluminum species in zeolites.
Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed, 132 citations in OpenAlex.
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- Unveiling the thermodynamic-kinetic trade-off effect on acid sites in zeolite-catalyzed alcohol dehydration.Nature communications · 2026Article
- Aluminum speciation identification reveals water interactions in silicoaluminophosphate zeolites.Proceedings of the National Academy of Sciences of the United States of America · 2025Article
- Evidence of Preferential Aluminum Site Loss during Reaction-Induced Dealumination.Journal of the American Chemical Society · 2024Article
- Lewis Acidic Aluminosilicates: Synthesis,Inorganic chemistry · 2024Article
- Precise Confinement and Position Distribution of Atomic Cu and Zn in ZSM-5 for CONanomaterials (Basel, Switzerland) · 2023Article
- Atomic Layer Deposition of the Geometry Separated Lewis and Brønsted Acid Sites for Cascade Glucose Conversion.JACS Au · 2023Article
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- A Comprehensive Review on Zeolite Chemistry for Catalytic Conversion of Biomass/Waste into Green Fuels.Molecules (Basel, Switzerland) · 2022Review
- High-Field NMR, Reactivity, and DFT Modeling Reveal the γ-AlAngewandte Chemie (International ed. in English) · 2022Article
- Recent advances in solid-state NMR of zeolite catalysts.National science review · 2022Review
- Emerging analytical methods to characterize zeolite-based materials.National science review · 2022Review
- Thermal Alteration in Adsorption Sites over SAPO-34 Zeolite.Angewandte Chemie (International ed. in English) · 2022Article
- Accurate heteronuclear distance measurements at all magic-angle spinning frequencies in solid-state NMR spectroscopy.Chemical science · 2021Article
- Distribution of Aluminum Species in Zeolite Catalysts:Journal of the American Chemical Society · 2021Article
- On the location of Lewis acidic aluminum in zeolite mordenite and the role of framework-associated aluminum in mediating the switch between Brønsted and Lewis acidity.Chemical science · 2021Article
- Catalytic Upgrading of Lignocellulosic Biomass Sugars Toward Biofuel 5-Ethoxymethylfurfural.Frontiers in chemistry · 2021Review
- Solid-stateNature protocols · 2020Article
- Deactivation of Cu-Exchanged Automotive-Emission NHAngewandte Chemie (International ed. in English) · 2020Article
Corrections and comments
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Authors and funding
11 authors at 2 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The unambiguous characterization of different acid sites in zeolites is of great importance for understanding their catalytic performance and the rational design of highly efficient zeolite catalysts. In addition to various well-characterized extra-framework Al species, a tri-coordinated framework aluminum species can also serve as a Lewis acid site in zeolites, which is "NMR-invisible" owing to its extremely distorted local environment. Here we provide a feasible and reliable approach to elucidate the acidic nature of the tri-coordinated framework Al in dehydrated H-ZSM-5 zeolites
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