ArticleChemistry (Weinheim an der Bergstrasse, Germany)2020
Magnesocenophane-Catalyzed Amine Borane Dehydrocoupling.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Two active species from a single metal halide precursor: a case study of highly productive Mn-catalyzed dehydrogenation of amine-boranesChemical science · 2024Article
- Main-Group Metallocenophanes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Review
- Bifunctional activation of amine-boranes by the W/Pd bimetallic analogs of "frustrated Lewis pairs".Chemical science · 2021Article
- Donor-Stabilized Monocarba-Bridged Bis(cyclopentadienyl)alanes.ChemistryOpen · 2020Article
- Magnesocenophane-Catalyzed Amine Borane Dehydrocoupling.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
The Lewis acidities of a series of [n]magnesocenophanes (1 a-d) have been investigated computationally and found to be a function of the tilt of the cyclopentadienyl moieties. Their catalytic abilities in amine borane dehydrogenation/dehydrocoupling reactions have been probed, and C[1]magnesocenophane (1 a) has been shown to effectively catalyze the dehydrogenation/dehydrocoupling of dimethylamine borane (2 a) and diisopropylamine borane (2 b) under ambient conditions. Furthermore, the mechanism of the reaction with 2 a has been investigated experimentally and computationally, and the results imply a ligand-assisted mechanism involving stepwise proton and hydride transfer, with dimethylaminoborane as the key intermediate.
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Registered trials
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