ArticleAngewandte Chemie (International ed. in English)2020
Disentangling Reaction Processes of Zeolites within Single-Oriented Channels.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Spatial Evolution of Coke in ZSM-5 Catalysts During Methanol-to-Hydrocarbons Conversion Revealed by In Situ X-Ray Photoelectron Spectroscopy.Angewandte Chemie (International ed. in English) · 2026Article
- Multiscale spatiotemporal heterogeneity of zeolite-catalyzed methanol-to-hydrocarbons reaction.National science review · 2026Review
- Pushing the limit of stability.National science review · 2024Article
- Article
- A Comprehensive Review on Zeolite Chemistry for Catalytic Conversion of Biomass/Waste into Green Fuels.Molecules (Basel, Switzerland) · 2022Review
- Electron Diffraction Enables the Mapping of Coke in ZSM-5 Micropores Formed during Methanol-to-Hydrocarbons Conversion.Angewandte Chemie (International ed. in English) · 2022Article
- Unravelling Channel Structure-Diffusivity Relationships in Zeolite ZSM-5 at the Single-Molecule Level.Angewandte Chemie (International ed. in English) · 2022Article
- A diffusion anisotropy descriptor links morphology effects of H-ZSM-5 zeolites to their catalytic cracking performance.Communications chemistry · 2021Article
- Elucidating Zeolite Channel Geometry-Reaction Intermediate Relationships for the Methanol-to-Hydrocarbon Process.Angewandte Chemie (International ed. in English) · 2020Article
- Disentangling Reaction Processes of Zeolites within Single-Oriented Channels.Angewandte Chemie (International ed. in English) · 2020Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
Establishing structure-reactivity relationships for specific channel orientations of zeolites is vital to developing new, superior materials for various applications, including oil and gas conversion processes. Herein, a well-defined model system was developed to build structure-reactivity relationships for specific zeolite-channel orientations during various catalytic reaction processes, for example, the methanol- and ethanol-to-hydrocarbons (MTH and ETH) process as well as oligomerization reactions. The entrapped and effluent hydrocarbons from single-oriented zeolite ZSM-5 channels during the MTH process were monitored by using operando UV/Vis diffuse reflectance spectroscopy (DRS) and on-line mass spectrometry (MS), respectively. The results reveal that the straight channels favor the formation of internal coke, promoting the aromatic cycle. Furthermore, the sinusoidal channels produce aromatics, (e.g., toluene) that further grow into larger polyaromatics (e.g., graphitic coke) leading to deactivation of the zeolites. This underscores the importance of careful engineering of materials to suppress coke formation and tune product distribution by rational control of the location of zeolite acid sites and crystallographic orientations.
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