Nickel-Catalyzed Removal of Alkene Protecting Group of Phenols, Alcohols via Chain Walking Process.

Chenkai Meng, Haolin Niu, Juehan Ning, Wengang Wu, Jun Yi

Abstract read

In one paragraph

Article in Molecules (Basel, Switzerland), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it

0cells of the map it votes in

1citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

Nickel-Catalyzed Reductive Cyanation of Aryl Halides and Epoxides with Cyanogen Bromide.Molecules (Basel, Switzerland) · 2024
Article

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Chenkai MengJiangsu Laboratory of Advanced Functional Material, School of Materials Engineering, Changshu Institute of Technology, Changshu 215500, China.

Haolin NiuJiangsu Laboratory of Advanced Functional Material, School of Materials Engineering, Changshu Institute of Technology, Changshu 215500, China.

Juehan NingJiangsu Laboratory of Advanced Functional Material, School of Materials Engineering, Changshu Institute of Technology, Changshu 215500, China.

Wengang WuJiangsu Laboratory of Advanced Functional Material, School of Materials Engineering, Changshu Institute of Technology, Changshu 215500, China.

Jun YiJiangsu Laboratory of Advanced Functional Material, School of Materials Engineering, Changshu Institute of Technology, Changshu 215500, China.

Funding

National Natural Science Foundation of China 21602017Natural Science Foundation of Jiangsu Province BK20160405Research Start-up Fund of Changshu Institute of Technology No. XZ1508

6 · The paper itself

Abstract

An efficient nickel-catalyzed removal of alkene protection group under mild condition with high functional group tolerance through chain walking process has been established. Not only phenolic ethers, but also alcoholic ethers can be tolerated with the retention of stereocenter adjacent to hydroxyl group. The new reaction brings the homoallyl group into a start of new type of protecting group.

Indexed as

AlcoholsAlkenesCatalysisMolecular StructureNickelPhenolsAlcoholsAlkenesNickelPhenolsalcoholchain walkingdeprotectionnickelphenol

Identifiers

PMID32019185

DOI10.3390/molecules25030602

PMCPMC7037277

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.