Evidence map›Paper›PMID 32012430›Full record

ArticleChemistry, an Asian journal2020

How Alkali Cations Catalyze Aromatic Diels-Alder Reactions.

Pascal Vermeeren, Francine Brinkhuis, Trevor A Hamlin, F Matthias Bickelhaupt

Abstract read
In one paragraph

Article in Chemistry, an Asian journal, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.

0numbers the graph read from it
0cells of the map it votes in
13citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

13 citing papers in PubMed.

  1. Article
  2. How Ionization Catalyzes Diels-Alder Reactions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022
    Article
  3. Origin of asynchronicity in Diels-Alder reactions.Physical chemistry chemical physics : PCCP · 2021
    Article
  4. Article
  5. Chemical reactivity from an activation strain perspective.Chemical communications (Cambridge, England) · 2021
    Review
  6. Article
  7. How Oriented External Electric Fields Modulate Reactivity.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021
    Article
  8. Article
  9. Article
  10. How Lewis Acids Catalyze Ring-Openings of Cyclohexene Oxide.The Journal of organic chemistry · 2021
    Article
  11. Article
  12. How Lewis Acids Catalyze Diels-Alder Reactions.Angewandte Chemie (International ed. in English) · 2020
    Article
  13. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Pascal VermeerenDepartment of Theoretical Chemistry Amsterdam Institute of Molecular and Life Sciences (AIMMS) Amsterdam Center for Multiscale Modeling (ACMM), Vrije Universiteit Amsterdam, De Boelelaan 1083, 1081 HV, Amsterdam (The, Netherlands.ORCID http://orcid.org/0000-0002-2100-6837
Francine BrinkhuisDepartment of Theoretical Chemistry Amsterdam Institute of Molecular and Life Sciences (AIMMS) Amsterdam Center for Multiscale Modeling (ACMM), Vrije Universiteit Amsterdam, De Boelelaan 1083, 1081 HV, Amsterdam (The, Netherlands.ORCID http://orcid.org/0000-0003-3134-3148
Trevor A HamlinDepartment of Theoretical Chemistry Amsterdam Institute of Molecular and Life Sciences (AIMMS) Amsterdam Center for Multiscale Modeling (ACMM), Vrije Universiteit Amsterdam, De Boelelaan 1083, 1081 HV, Amsterdam (The, Netherlands.ORCID http://orcid.org/0000-0002-5128-1004
F Matthias BickelhauptDepartment of Theoretical Chemistry Amsterdam Institute of Molecular and Life Sciences (AIMMS) Amsterdam Center for Multiscale Modeling (ACMM), Vrije Universiteit Amsterdam, De Boelelaan 1083, 1081 HV, Amsterdam (The, Netherlands.ORCID http://orcid.org/0000-0003-4655-7747

Funding

Dutch Astrochemistry NetworkNetherlands Organization for Scientific Research
6 · The paper itself

Abstract

We have quantum chemically studied alkali cation-catalyzed aromatic Diels-Alder reactions between benzene and acetylene forming barrelene using relativistic, dispersion-corrected density functional theory. The alkali cation-catalyzed aromatic Diels-Alder reactions are accelerated by up to 5 orders of magnitude relative to the uncatalyzed reaction and the reaction barrier increases along the series Li

Indexed as

Activation Strain ModelAlkali CationAromatic Diels-Alder ReactionDensity Functional CalculationsReactivity

Identifiers

PMID32012430
PMCPMC7187256

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.