ArticleDental materials : official publication of the Academy of Dental Materials2020
Effect of the photoinitiator system on the polymerization of secondary methacrylamides of systematically varied structure for dental adhesive applications.
Article in Dental materials : official publication of the Academy of Dental Materials, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed, 31 citations in OpenAlex.
- Enhancing dentin bonding with catechol-based monomers by tailoring photoinitiator systems to overcome radical inhibition.Dental materials : official publication of the Academy of Dental Materials · 2026Article
- Initiator-dependent effects of thiourethane on resin cement curing under light attenuation conditions.Dental materials : official publication of the Academy of Dental Materials · 2026Article
- Article
- Improvement of dentin bonding via adhesive monomers with multiple hydrogen bonding moieties.Acta biomaterialia · 2025Article
- Photoinitiators for Medical Applications-The Latest Advances.Molecules (Basel, Switzerland) · 2024Review
- Replica-mold nanopatterned PHEMA hydrogel surfaces for ophthalmic applications.Scientific reports · 2022Article
- Rheological and Mechanical Properties of Resin-Based Materials Applied in Dental Restorations.Polymers · 2021Review
- Effect of side-group methylation on the performance of methacrylamides and methacrylates for dentin hybridization.Dental materials : official publication of the Academy of Dental Materials · 2021Article
- Synthesis of di- and triacrylamides with tertiary amine cores and their evaluation as monomers in dental adhesive interfaces.Acta biomaterialia · 2020Article
- Alternative monomer for BisGMA-free resin composites formulations.Dental materials : official publication of the Academy of Dental Materials · 2020Article
- Effect of a polymerization inhibitor on the chemomechanical properties and consistency of experimental resin composites.Brazilian dental journalArticle
Corrections and comments
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Authors and funding
8 authors at 2 institutions in 2 countries.
Funding
Abstract
objectiveThe aim of this study was to investigate the influence of the photoinitiator system on the polymerization kinetics of methacrylamide-based monomers as alternatives to methacrylates in adhesives dental-based materials.
methodsIn total, 16 groups were tested. Monofunctional monomers (2-hydroxyethyl methacrylate) - HEMA; (2-hydroxy-1-ethyl methacrylate) -2EMATE, (2-hydroxyethyl methacrylamide) - HEMAM; and (N-(1-hydroxybutan-2-yl) methacrylamide) -2EM; were combined with bifunctional monomers containing the same polymerizing moieties as the monofunctional counterparts (HEMA-BDI; 2EMATE-BDI; HEMAM-BDI; and 2EM-BDI) at 50/50 M ratios. BHT was used as inhibitor (0.1 wt%) and the photoinitiators used were: CQ + EDMAB (0.2/0.8), BAPO (0.2), IVOCERIN (0.2), and DMPA (0.2), in wt%. The polymerization kinetics were monitored using Near-IR spectroscopy (∼6165 cm
resultsThere was statistically significant interaction between monomer and photoinitiator (p < 0.001). For the methacrylates groups, the highest Rp SIGNIFICANCE: this work demonstrated the feasibility of using newly-synthesized methacrylamide monomers in conjunction with a series of initiator systems already used in commercial materials.
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Registered trials
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