ArticleJournal of the American Chemical Society2020
Engineering a Highly Defective Stable UiO-66 with Tunable Lewis- Brønsted Acidity: The Role of the Hemilabile Linker.
Article in Journal of the American Chemical Society, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 33 papers.
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Who cites it
33 citing papers in PubMed.
- One-Step Separation of Propylene From Ternary CSmall (Weinheim an der Bergstrasse, Germany) · 2026Article
- Node Distortions as a Means of Defect Engineering in Zr-Based MOFs.Journal of the American Chemical Society · 2026Article
- Moisture sorption and hydration dynamics in intrinsically hygroscopic hydrogels.Science advances · 2026Article
- UiO-type metal - organic frameworks as a platform for hydrogen storage studies.Science and technology of advanced materials · 2026Review
- Modulator Control of Cation Distribution in Mixed-Metal UiO-66(Zr,Ce) Metal-Organic Frameworks.Chemistry of materials : a publication of the American Chemical Society · 2025Article
- Beyond Density: Unveiling the Trade-Off in Catalytic Site Optimization Using Defect-Engineered UiO-66.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Fluorinated Zirconium-Based Metal-Organic Frameworks as Novel Sorbents to Improve the Efficacy of Hemodialysis Treatment.Small science · 2025Article
- Tailored engineering of primary catalytic sites and secondary coordination spheres in metalloenzyme-mimetic MOF catalysts for boosting efficient COChemical science · 2025Article
- Controlled Growth of Highly Defected Zirconium-Metal-Organic Frameworks via a Reaction-Diffusion System for Water Remediation.ACS applied materials & interfaces · 2025Review
- Entropy engineering activation of UiO-66 for boosting catalytic transfer hydrogenation.Nature communications · 2025Article
- Electrochemical Selective Removal of Oxyanions in a Ferrocene-Doped Metal-Organic Framework.ACS nano · 2024Article
- Manipulation of interfacial charge dynamics for metal-organic frameworks toward advanced photocatalytic applications.Nanoscale advances · 2024Review
- Detangling electrolyte chemical dynamics in lithium sulfur batteries by operando monitoring with optical resonance combs.Nature communications · 2023Article
- Synthetic control of correlated disorder in UiO-66 frameworks.Nature communications · 2023Article
- Implementing Mesoporosity in Zeolitic Imidazolate Frameworks through Clip-Off Chemistry in Heterometallic Iron-Zinc ZIF-8.Journal of the American Chemical Society · 2023Article
- Challenges in modelling dynamic processes in realistic nanostructured materials at operating conditions.Philosophical transactions. Series A, Mathematical, physical, and engineering sciences · 2023Review
- Tailoring and Identifying Brønsted Acid Sites on Metal Oxo-Clusters of Metal-Organic Frameworks for Catalytic Transformation.ACS central science · 2023Article
- Metal Node Control of Brønsted Acidity in Heterobimetallic Titanium-Organic Frameworks.Journal of the American Chemical Society · 2023Article
- Switchable Metal Sites in Metal-Organic Framework MFM-300(Sc): Lewis Acid Catalysis Driven by Metal-Hemilabile Linker Bond Dynamics.Angewandte Chemie (International ed. in English) · 2022Article
- 2D MOF with Compact Catalytic Sites for the One-pot Synthesis of 2,5-Dimethylfuran from Saccharides via Tandem Catalysis.Angewandte Chemie (International ed. in English) · 2022Article
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Authors and funding
15 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The stability of metal-organic frameworks (MOFs) typically decreases with an increasing number of defects, limiting the number of defects that can be created and limiting catalytic and other applications. Herein, we use a hemilabile (Hl) linker to create up to a maximum of six defects per cluster in UiO-66. We synthesized hemilabile UiO-66 (Hl-UiO-66) using benzene dicarboxylate (BDC) as linker and 4-sulfonatobenzoate (PSBA) as the hemilabile linker. The PSBA acts not only as a modulator to create defects but also as a coligand that enhances the stability of the resulting defective framework. Furthermore, upon a postsynthetic treatment in H
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Registered trials
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