ArticleThe Journal of organic chemistry2020
A Covalent and Modular Synthesis of Homo- and Hetero[
Article in The Journal of organic chemistry, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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The trial behind it
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Who cites it
7 citing papers in PubMed.
- Covalent Templated Catenane Synthesis Requiring Hindered Ester Cleavage.The Journal of organic chemistry · 2026Article
- Covalent-Bond-Directed Synthesis of Rotaxanes from Macrocyclic Diaryliodonium Salts.Organic letters · 2026Article
- Covalent Template-Directed Synthesis: A Powerful Tool for the Construction of Complex Molecules.Chemical reviews · 2025Review
- Distinctive features and challenges in catenane chemistry.Chemical science · 2022Review
- Self-Assembly of Stimuli-Responsive [2]Rotaxanes by Amidinium Exchange.Journal of the American Chemical Society · 2021Article
- [2]Catenane Synthesis via Covalent Templating.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- A precise polyrotaxane synthesizer.Science (New York, N.Y.) · 2020Article
Corrections and comments
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Incorporation of 2,5-dihydroxyterephthalate as a covalent scaffold in the axis of a 30-membered all-carbon macrocycle provides access to a modular series of rotaxanes. Installment of tethered alkynes or azides onto the terephthalic phenolic hydroxyl functionalities, which are situated at opposite sides of the macrocycle, gives versatile prerotaxane building blocks. The corresponding [2]rotaxanes are obtained by introduction of bulky stoppering ("capping") units at the tethers and subsequent cleavage of the covalent ring/thread ester linkages. Extension of this strategy via coupling of two prerotaxanes bearing complementary linker functionalities (i.e., azide and alkyne) and follow-up attachment of stopper groups provide efficient access to [
Identifiers
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Registered trials
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