ArticleChemistry (Weinheim an der Bergstrasse, Germany)2020
Ambident Nucleophilic Substitution: Understanding Non-HSAB Behavior through Activation Strain and Conceptual DFT Analyses.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Computational Study on the Co-Mediated Intramolecular Pauson-Khand Reaction of Fluorinated and ChiralOrganometallics · 2022Article
- Pd-Catalyzed Chemoselective O‑Benzylation of Ambident 2‑Quinolinone Nucleophiles.ACS catalysis · 2022Article
- High-Level Systematic Ab Initio Comparison of Carbon- and Silicon-Centered SThe journal of physical chemistry. A · 2021Article
- Chemical reactivity from an activation strain perspective.Chemical communications (Cambridge, England) · 2021Review
- Nature and Strength of Lewis Acid/Base Interaction in Boron and Nitrogen Trihalides.Chemistry, an Asian journal · 2020Article
- How Do Local Reactivity Descriptors Shape the Potential Energy Surface Associated with Chemical Reactions? The Valence Bond Delocalization Perspective.Journal of the American Chemical Society · 2020Article
- Ambident Nucleophilic Substitution: Understanding Non-HSAB Behavior through Activation Strain and Conceptual DFT Analyses.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
The ability to understand and predict ambident reactivity is key to the rational design of organic syntheses. An approach to understand trends in ambident reactivity is the hard and soft acids and bases (HSAB) principle. The recent controversy over the general validity of this principle prompted us to investigate the competing gas-phase S
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Registered trials
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