Evidence map›Paper›PMID 31953874›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2020

Identification of the Active Catalyst for Nickel-Catalyzed Stereospecific Kumada Coupling Reactions of Ethers.

David D Dawson, Victoria F Oswald, Andy S Borovik, Elizabeth R Jarvo

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. A Bench-Stable Fluorophosphine Nickel(0) Complex and Its Catalytic Application.Angewandte Chemie (International ed. in English) · 2025
    Article
  2. Article
  3. Article
  4. Article
  5. Harnessing C-O Bonds in Stereoselective Cross-Coupling and Cross-Electrophile Coupling Reactions.Synlett : accounts and rapid communications in synthetic organic chemistry · 2021
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

David D DawsonDepartment of Chemistry, University of California, Irvine, Irvine, CA, 92697, USA.
Victoria F OswaldDepartment of Chemistry, University of California, Irvine, Irvine, CA, 92697, USA.
Andy S BorovikDepartment of Chemistry, University of California, Irvine, Irvine, CA, 92697, USA.
Elizabeth R JarvoDepartment of Chemistry, University of California, Irvine, Irvine, CA, 92697, USA.ORCID http://orcid.org/0000-0002-2818-4038

Funding

Upgrade for an Electron Paramagnetic Resonance SpectrometerR37GM050781 · NIGMS · UNIVERSITY OF CALIFORNIA-IRVINE · PI BOROVIK, ANDREW S. · 2016 to 2025
$4.1M
HYDROGEN BONDING CAVITY MOTIFS ABOUT METAL IONSR01GM050781 · NIGMS · UNIVERSITY OF KANSAS LAWRENCE · PI BOROVIK, ANDREW S. · 1999 to 2015
$3.9M
National Science Foundation NSF-CHE-1464980NIGMS NIH HHS R01 GM050781NIGMS NIH HHS R37 GM050781NIH HHS NIH GM050781
6 · The paper itself

Abstract

A series of nickel complexes in varying oxidation states were evaluated as precatalysts for the stereospecific cross-coupling of benzylic ethers. These results demonstrate rapid redox reactions of precatalysts, such that the oxidative state of the precatalyst does not dictate the oxidation state of the active catalyst in solution. These data provide the first experimental evidence for a Ni

Indexed as

absorption spectroscopycross-coupling mechanismnickel catalysisorganic chemistryprecatalyst

Identifiers

PMID31953874
PMCPMC7872209

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.