ArticleNature communications2020
Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms.
Article in Nature communications, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 26 papers.
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Who cites it
26 citing papers in PubMed.
- Transient Triamidoamine Neptunium(V)-Mono(Imido) Complexes: C-H Activations and Hydrogen Atom Transfer Driven by Effective Nuclear Charge.Journal of the American Chemical Society · 2026Article
- Ruthenium Complexes Containing Pyridinyl-Derived Ligands as FLP Catalysts.Inorganic chemistry · 2026Article
- Hydrosilylation of a Molecular Molybdenum Nitride Provides Mechanistic Insights into Photodriven Ammonia Synthesis from NJournal of the American Chemical Society · 2026Article
- Catalytic and stoichiometric stepwise conversion of side-on bound dinitrogen to ammonia mediated by a uranium complex.Nature chemistry · 2025Article
- A tetrahedral neptunium(V) complex.Nature chemistry · 2024Article
- Proton-Coupled Electron Transfer at the PuJournal of the American Chemical Society · 2024Article
- Progress in Nonaqueous Molecular Uranium Chemistry: Where to Next?Inorganic chemistry · 2024Article
- Arene-, Chlorido-, and Imido-Uranium Bis- and Tris(boryloxide) Complexes.Inorganic chemistry · 2024Article
- An orbitally adapted push-pull template for NChemical science · 2023Article
- Progress in the chemistry of molecular actinide-nitride compounds.Chemical science · 2023Review
- Current Strategies for Engineered Vascular Grafts and Vascularized Tissue Engineering.Polymers · 2023Review
- Facile Synthesis of Uranium Complexes with a Pendant Borane Lewis Acid and 1,2-Insertion of CO into a U-N Bond.Angewandte Chemie (International ed. in English) · 2022Article
- Reactions of Frustrated Lewis Pairs with Chloro-Diazirines: Cleavage of N=N Double Bonds.Angewandte Chemie (International ed. in English) · 2022Article
- Cation assisted binding and cleavage of dinitrogen by uranium complexes.Chemical science · 2022Article
- Photochemical Synthesis of Transition Metal-Stabilized Uranium(VI) Nitride Complexes.Nature communications · 2022Article
- Uranium-nitride chemistry: uranium-uranium electronic communication mediated by nitride bridges.Dalton transactions (Cambridge, England : 2003) · 2022Article
- Geometrical influence on the non-biomimetic heterolytic splitting of HChemical science · 2022Article
- Uranium: The Nuclear Fuel Cycle and Beyond.International journal of molecular sciences · 2022Review
- Insights into the Electronic Structure of a U(IV) Amido and U(V) Imido Complex.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- A thiolate-bridged FeNature chemistry · 2022Article
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Authors and funding
9 authors.
Funding
Abstract
Despite their importance as mechanistic models for heterogeneous Haber Bosch ammonia synthesis from dinitrogen and dihydrogen, homogeneous molecular terminal metal-nitrides are notoriously unreactive towards dihydrogen, and only a few electron-rich, low-coordinate variants demonstrate any hydrogenolysis chemistry. Here, we report hydrogenolysis of a terminal uranium(V)-nitride under mild conditions even though it is electron-poor and not low-coordinate. Two divergent hydrogenolysis mechanisms are found; direct 1,2-dihydrogen addition across the uranium(V)-nitride then H-atom 1,1-migratory insertion to give a uranium(III)-amide, or with trimesitylborane a Frustrated Lewis Pair (FLP) route that produces a uranium(IV)-amide with sacrificial trimesitylborane radical anion. An isostructural uranium(VI)-nitride is inert to hydrogenolysis, suggesting the 5f
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