ArticleAngewandte Chemie (International ed. in English)2020
Active and Unidirectional Acceleration of Biaryl Rotation by a Molecular Motor.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 35 papers.
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Who cites it
35 citing papers in PubMed.
- A supercharged molecular motor operating by constitutional alteration and proton transfer.Nature chemistry · 2026Article
- Multistate photoswitches beyond on and off.Nature communications · 2026Review
- Molecular Photogearing for Controlling Rotary Motion at the Nanoscale.ChemPlusChem · 2026Article
- A Catalysis-Driven Dual Molecular Motor.Journal of the American Chemical Society · 2025Article
- Hemiphosphoindigos as a platform for chiroptical or water soluble photoswitching.Nature communications · 2025Article
- Coupling Rotary Motion to Helicene Inversion within a Molecular Motor.Angewandte Chemie (International ed. in English) · 2025Article
- Directionality Reversal and Shift of Rotational Axis in a Hemithioindigo Macrocyclic Molecular Motor.Journal of the American Chemical Society · 2024Article
- Coupled Rocking Motion in a Light-Driven Rotary Molecular Motor.The Journal of organic chemistry · 2024Article
- Proton-Coupled Photochromic Hemithioindigo: Toward Photoactivated Chemical Sensing and Imaging.Analytical chemistry · 2023Article
- Controlling Swing Rates in Macrocyclic Molecular Mortise Hinges.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- A photochemical method to evidence directional molecular motions.Nature communications · 2023Article
- Non-equilibrium Steady States in Catalysis, Molecular Motors, and Supramolecular Materials: Why Networks and Language Matter.Journal of the American Chemical Society · 2023Review
- Defining Unidirectional Motions and Structural Reconfiguration in a Macrocyclic Molecular Motor.Journal of the American Chemical Society · 2023Article
- A cross-conjugation approach for high-performance diaryl-hemithioindigo photoswitches.Chemical science · 2023Article
- Photoactivated Artificial Molecular Motors.JACS Au · 2023Review
- Coupled Rotary and Oscillatory Motion in a Second-Generation Molecular Motor Pd Complex.Journal of the American Chemical Society · 2023Article
- Heterocyclic Hemithioindigos: Highly Advantageous Properties as Molecular Photoswitches.Angewandte Chemie (International ed. in English) · 2022Article
- Chemically Driven Rotatory Molecular Machines.Angewandte Chemie (International ed. in English) · 2022Review
- The Influence of Strain on the Rotation of an Artificial Molecular Motor.Angewandte Chemie (International ed. in English) · 2022Article
- Through the Eyes of Creators: Observing Artificial Molecular Motors.ACS nanoscience Au · 2022Review
Corrections and comments
- Erratum issued
Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Light-driven molecular motors possess immense potential as central driving units for future nanotechnology. Integration into larger molecular setups and transduction of their mechanical motions represents the current frontier of research. Herein we report on an integrated molecular machine setup allowing the transmission of potential energy from a motor unit onto a remote receiving entity. The setup consists of a motor unit connected covalently to a distant and sterically encumbered biaryl receiver. By action of the motor unit, single-bond rotation of the receiver is strongly accelerated and forced to proceed unidirectionally. The transmitted potential energy is directly measured as the extent to which energy degeneration is lifted in the thermal atropisomerization of this biaryl. Energy degeneracy is reduced by more than 1.5 kcal mol
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