Cationic Copolymerization of Isobutylene with 4-Vinylbenzenecyclobutylene: Characteristics and Mechanisms.

Zhifei Chen, Shuxin Li, Yuwei Shang, Shan Huang, Kangda Wu, Wenli Guo, Yibo Wu

Abstract read

In one paragraph

Article in Polymers, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

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2citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

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Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

Near-Infrared Light-Responsive Shell-Crosslinked Micelles of Poly(d,l-lactide)-Materials (Basel, Switzerland) · 2021
Article
The Scissors Effect in Action: The Fox-Flory Relationship between the Glass Transition Temperature of Crosslinked Poly(Methyl Methacrylate) and Mc in Nanophase Separated Poly(Methyl Methacrylate)-Materials (Basel, Switzerland) · 2020
Article

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PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Zhifei ChenBeijing Key Lab of Special Elastomeric Composite Materials, Department of Materials Science and Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China.

Shuxin LiBeijing Key Lab of Special Elastomeric Composite Materials, Department of Materials Science and Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China.

Yuwei ShangBeijing Key Lab of Special Elastomeric Composite Materials, Department of Materials Science and Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China.

Shan HuangBeijing Key Lab of Special Elastomeric Composite Materials, Department of Materials Science and Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China.

Kangda WuBeijing Key Lab of Special Elastomeric Composite Materials, Department of Materials Science and Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China.

Wenli GuoBeijing Key Lab of Special Elastomeric Composite Materials, Department of Materials Science and Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China.

Yibo WuBeijing Key Lab of Special Elastomeric Composite Materials, Department of Materials Science and Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China.ORCID 0000-0002-3739-4643

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

A random copolymer of isobutylene (IB) and 4-vinylbenzenecyclobutylene (4-VBCB) was synthesized by cationic polymerization at -80 °C using 2-chloro-2,4,4-trimethylpentane (TMPCl) as initiator. The laws of copolymerization were investigated by changing the feed quantities of 4-VBCB. The molecular weight of the copolymer decreased, and its molecular weight distribution (MWD) increased with increasing 4-VBCB content. We proposed a possible copolymerization mechanism behind the increase in the chain transfer reaction to 4-VBCB with increasing of feed quantities of 4-VBCB. The thermal properties of the copolymers were studied by solid-phase heating and crosslinking. After crosslinking, the decomposition and glass transition temperatures (

Indexed as

4-vinylbenzocyclobutenecationic polymerizationcrosslinkrandom copolymer

Identifiers

PMID31941043

DOI10.3390/polym12010201

PMCPMC7023408

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.