Evidence map›Paper›PMID 31921520›Full record

ArticleBeilstein journal of nanotechnology2019

Air oxidation of sulfur mustard gas simulants using a pyrene-based metal-organic framework photocatalyst.

Ghada Ayoub, Mihails Arhangelskis, Xuan Zhang, Florencia Son, Timur Islamoglu, Tomislav Friščić, Omar K Farha

Open access · diamondAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Beilstein journal of nanotechnology, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
0.8field-weighted citation impact, top 29% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed, 21 citations in OpenAlex.

  1. Review
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors at 2 institutions in 2 countries.

Ghada AyoubDepartment of Chemistry, McGill University, Montreal, Quebec, H3A 0B8, Canada.ORCID https://orcid.org/0000-0002-5864-8681
Mihails ArhangelskisDepartment of Chemistry, McGill University, Montreal, Quebec, H3A 0B8, Canada.ORCID https://orcid.org/0000-0003-1150-3108
Xuan ZhangInternational Institute of Nanotechnology, Department of Chemistry, Northwestern University, 2145 Sheridan Rd, Evanston, IL 60208, USA.ORCID https://orcid.org/0000-0001-8214-7265
Florencia SonInternational Institute of Nanotechnology, Department of Chemistry, Northwestern University, 2145 Sheridan Rd, Evanston, IL 60208, USA.ORCID https://orcid.org/0000-0002-7524-3774
Timur IslamogluInternational Institute of Nanotechnology, Department of Chemistry, Northwestern University, 2145 Sheridan Rd, Evanston, IL 60208, USA.ORCID https://orcid.org/0000-0003-3688-9158
Tomislav FriščićDepartment of Chemistry, McGill University, Montreal, Quebec, H3A 0B8, Canada.ORCID https://orcid.org/0000-0002-3921-7915
Omar K FarhaInternational Institute of Nanotechnology, Department of Chemistry, Northwestern University, 2145 Sheridan Rd, Evanston, IL 60208, USA.ORCID https://orcid.org/0000-0002-9904-9845
Northwestern University · USMcGill University · CA

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

We demonstrate a microporous metal-organic framework NU-400 based on a 2,7-disubstituted pyrene linker as a highly efficient photosensitizer for generating singlet oxygen and subsequent oxidative degradation of chemical warfare agents (CWAs). The high activity of NU-400 permits photocatalytic conversion of the 2-chloroethyl ethyl sulfide (CEES) mustard gas simulant into a benign sulfoxide derivative, in air, with less than 15 minutes' half-life. This is a considerable improvement to NU-1000, based on a 1,3,6,8-tetrasubstituted pyrene unit, demonstrating how variation of the substitution pattern of a metal-organic framework linker permits modification of its photoactive behavior.

Indexed as

metal-organic frameworksoxidationphotocatalysissinglet oxygensulfur mustard gas

Identifiers

PMID31921520
PMCPMC6941406
OpenAlexW2991870476

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.