Evidence map›Paper›PMID 31919738›Full record

ArticleMolecular diversity2021

Regioselective and stereoselective synthesis of epithiomethanoiminoindeno[1,2-b]furan-3-carbonitrile: heterocyclic [3.3.3]propellanes.

Alaa A Hassan, Nasr K Mohamed, Ashraf A Aly, Hendawy N Tawfeek, Stefan Bräse, Martin Nieger

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Article in Molecular diversity, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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4 · The record

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5 · Who and what money

Authors and funding

6 authors.

Alaa A HassanChemistry Department, Faculty of Science, Minia University, El-Minia, 61519, Egypt. alaahassan2001@mu.edu.eg.ORCID http://orcid.org/0000-0001-9193-560X
Nasr K MohamedChemistry Department, Faculty of Science, Minia University, El-Minia, 61519, Egypt.
Ashraf A AlyChemistry Department, Faculty of Science, Minia University, El-Minia, 61519, Egypt.
Hendawy N TawfeekChemistry Department, Faculty of Science, Minia University, El-Minia, 61519, Egypt.
Stefan BräseInstitute of Organic Chemistry, Karlsruhe Institute of Technology, Fritz-Haber-Weg 6, 76131, Karlsruhe, Germany.
Martin NiegerDepartment of Chemistry, University of Helsinki, P.O. Box 55, A. I. Virtasen aukio I, 00014, Helsinki, Finland.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Synthesis of heteropropellanes in one step: the reaction between dicyanomethylene-1,3-indanedione (CNIND) and N-substituted-2-(2,4-dinitrophenyl)hydrazinecarbothioamides, furnished (3aR,8bS,Z)-2-amino-9-substituted-10-(2-(2,4-dinitrophenyl)hydrazono)-4-oxo-4H-3a,8b-(epithiomethanoimino)indeno[1,2-b]furan-3-carbonitrile as a type of (2,4-dinitrophenyl)hydrazono[3.3.3]propellanes in good yields as single diastereomers. Structure determination and confirmation of the synthesized products have been achieved using various and modern spectroscopic techniques such as IR, NMR (

Indexed as

Crystallography, X-RayFuransHeterocyclic CompoundsMagnetic Resonance SpectroscopyfuranFuransHeterocyclic CompoundsAnnulated compoundsFurothiazolo[3.3.3]propellanesHeterocyclizationImine-enamine tautomerismNucleophilic additionThiosemicarbazides

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.