ArticleAngewandte Chemie (International ed. in English)2020
Acetylene as a Dicarbene Equivalent for Gold(I) Catalysis: Total Synthesis of Waitziacuminone in One Step.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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The trial behind it
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Who cites it
10 citing papers in PubMed, 50 citations in OpenAlex.
- Catalytic Generation of Cationic Gold Carbene Complexes From 7-Alkynylnorbornadienes and Their Intermolecular Cyclopropanation With Alkenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Gold(I)-Catalyzed Intermolecular Reactions of Alkynes with Carbon Nucleophiles: What We Knowand What We Don't.ACS catalysis · 2026Review
- Interrogating theJACS Au · 2025Article
- Three-Component Gold(I)-Catalyzed Alkoxyvinylation.Organic letters · 2024Article
- Gold(I)-Catalyzed Intermolecular Aryloxyvinylation with Acetylene Gas.ACS catalysis · 2023Article
- Synthesis of vinyl-substituted alcohols using acetylene as a C2 building block.Chemical science · 2023Article
- Cu-catalyzed carboboration of acetylene with Michael acceptors.Chemical science · 2022Article
- Gold-Catalyzed Synthesis of Small Rings.Chemical reviews · 2021Article
- Acetylene as a Dicarbene Equivalent for Gold(I) Catalysis: Total Synthesis of Waitziacuminone in One Step.Angewandte Chemie (International ed. in English) · 2020Article
- Recent Advances in Construction of Polycyclic Natural Product Scaffolds via One-Pot Reactions Involving Alkyne Annulation.Frontiers in chemistry · 2020Review
Corrections and comments
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Authors and funding
6 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The gold(I)-catalyzed reaction of acetylene gas with alkenes leads to (Z,Z)-1,4-disubstituted 1,3-butadienes and biscyclopropanes depending on the donor ligand on gold(I). Acetylene was generated in situ from calcium carbide and water in a user-friendly procedure. Reaction of acetylene with 1,5-dienes gives rise stereoselectively to tricyclo[5.1.0.0
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.