ArticleJournal of the American Chemical Society2020
Introducing Seven Transition Metal Ions into Terpyridine-Based Supramolecules: Self-Assembly and Dynamic Ligand Exchange Study.
Article in Journal of the American Chemical Society, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
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19 citing papers in PubMed.
- Triphenylamine-Based Supramolecular Coordination Metallacycles.Molecules (Basel, Switzerland) · 2026Review
- London Dispersion Governs Stereochemistry, Stability, and Self-Sorting in a System of MJournal of the American Chemical Society · 2026Article
- Colloidal Phase Control in Plasmonic Metal Oxide Nanocrystals via Competitive Metal-Ligand Equilibria.Angewandte Chemie (International ed. in English) · 2025Article
- Novel metallo-supramolecular architectures based on side-pyridine-modified terpyridines: design, self-assembly, and properties.Chemical science · 2025Review
- Construction of Heterometallic Coordination Nanosheets Comprising Both Inert and Labile Metal Ions Together via Metalloligand Approach.Inorganic chemistry · 2025Article
- Ion Mobility Mass Spectrometry for Large Synthetic Molecules: Expanding the Analytical Toolbox.Journal of the American Chemical Society · 2024Review
- Article
- Structure Transformation and Morphologic Modulation of Supramolecular Frameworks for Nanoseparation and Enzyme Loading.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Article
- Disassembly Mechanisms and Energetics of Polymetallic Rings and Rotaxanes.Journal of the American Chemical Society · 2022Article
- Controlling of Photophysical Behavior of Rhenium(I) Complexes with 2,6-Di(thiazol-2-yl)pyridine-Based Ligands by Pendant π-Conjugated Aryl Groups.International journal of molecular sciences · 2022Article
- Colorimetric quantification of linking in thermoreversible nanocrystal gel assemblies.Science advances · 2022Article
- Synthesis of an Fe(terpy-cage)RSC advances · 2022Article
- Designing narcissistic self-sorting terpyridine moieties with high coordination selectivity for complex metallo-supramolecules.Communications chemistry · 2021Article
- Paramagnetic solid-state NMR assignment and novel chemical conversion of the aldehyde group to dihydrogenRSC advances · 2021Article
- Stepwise introduction of three different transition metals in metallo-supramolecular polymer for quad-color electrochromism.Communications chemistry · 2021Article
- Multi-stimuli Control over Assembly and Guest Binding in Metallo-supramolecular Hosts Based on Dithienylethene Photoswitches.Journal of the American Chemical Society · 2021Article
- Reaction Monitoring and Structural Characterisation of Coordination Driven Self-Assembled Systems by Ion Mobility-Mass Spectrometry.Frontiers in chemistry · 2021Review
- Over one century after discovery: pyrylium salt chemistry emerging as a powerful approach for the construction of complex macrocycles and metallo-supramolecules.Chemical science · 2020Review
- Self-Assembly of Metallo-Supramolecules under Kinetic or Thermodynamic Control: Characterization of Positional Isomers Using Scanning Tunneling Spectroscopy.Journal of the American Chemical Society · 2020Article
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11 authors.
Funding
Abstract
In coordination-driven self-assembly, 2,2':6',2″-terpyridine (tpy) has gained extensive attention in constructing supramolecular architectures on the basis of ⟨tpy-M-tpy⟩ connectivity. In direct self-assembly of large discrete structures, however, the metal ions were mainly limited to Cd(II), Zn(II), and Fe(II) ions. Herein, we significantly broaden the spectrum of metal ions with seven divalent transition metal ions M(II) (M = Mn, Fe, Co, Ni, Cu, Zn, Cd) to assemble a series of supramolecular fractals. In particular, Mn(II), Co(II), Ni(II), and Cu(II) were reported for the first time to form such large and discrete structures with ⟨tpy-M-tpy⟩ connectivity. In addition, the structural stabilities of those supramolecules in the gas phase and the kinetics of the ligand exchange process in solution were investigated using mass spectrometry. Such a fundamental study gave the relative order of structural stability in the gas phase and revealed the inertness of coordination in solution depending on the metal ions. Those results would guide the future study in tpy-based supramolecular chemistry in terms of self-assembly, characterization, property, and application.
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