ArticleJournal of the American Chemical Society2020
Electrophotocatalytic C-H Functionalization of Ethers with High Regioselectivity.
Article in Journal of the American Chemical Society, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 42 papers.
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Who cites it
42 citing papers in PubMed.
- Stereoretentive Nucleophilic Aromatic Substitution Accesses Atropisomeric 4-Amino-N-Arylquinolinium Salts.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Photophysics of Doubly Reduced Quinacridone Dyes: Toward Redox Reactivity Activated by Red Light.Artificial photosynthesis (Washington, D.C.) · 2026Article
- Oxygen-enabled Fe-catalyzed heteroatom α-C(spChemical science · 2026Article
- Electrocatalytic C(spNature communications · 2026Article
- Dispersion-Enhanced Nitrogen-Centered Photocatalysis of the Direct Hydrogen Atom Transfer.Angewandte Chemie (International ed. in English) · 2026Article
- Two-step coupled photoelectrochemical chlorination and oxygenation of C(spChemical science · 2025Article
- Excited Organic Radicals in Photoredox Catalysis.JACS Au · 2025Review
- Electro-photochemical Functionalization of C(spJACS Au · 2024Review
- Metal-carbene-guided twofold cross-coupling of ethers with chromium catalysis.Nature communications · 2024Article
- Unlocking flavin photoacid catalysis through electrophotochemistry.Chemical science · 2024Article
- Photoelectrochemical Fe/Ni cocatalyzed C-C functionalization of alcohols.Nature communications · 2024Article
- Electrophotocatalytic hydrogenation of imines and reductive functionalization of aryl halides.Nature communications · 2024Article
- Selective C(spNature communications · 2023Article
- Photoelectrochemical oxidative C(spNature communications · 2023Article
- Electrochemical Late-Stage Functionalization.Chemical reviews · 2023Review
- Electrochemically Driven Hydrogen Atom Transfer Catalysis: A Tool for C(spACS catalysis · 2023Review
- Cu-catalyzed enantioselective decarboxylative cyanationChemical science · 2023Article
- Photoredox catalysis harvesting multiple photon or electrochemical energies.Beilstein journal of organic chemistry · 2023Review
- Catalytic Synthesis of Cyclopropenium Cations with Rh-Carbynoids.Journal of the American Chemical Society · 2022Article
- Ritter-type amination of C(spNature communications · 2022Article
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Authors and funding
3 authors.
Funding
Abstract
The highly regioselective electrophotocatalytic C-H functionalization of ethers is described. These reactions are catalyzed by a trisaminocyclopropenium (TAC) ion at mild electrochemical potential with visible light irradiation. Ethers undergo oxidant-free coupling with isoquinolines, alkenes, alkynes, pyrazoles, and purines with typically high regioselectivity for the less-hindered α-position. The reaction is proposed to operate via hydrogen atom transfer (HAT) from the substrate to the photoexcited TAC radical dication, thus demonstrating a new reactivity mode for this electrophotocatalyst.
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