ArticleJournal of the American Chemical Society2020
Visible Light-Induced Borylation of C-O, C-N, and C-X Bonds.
Article in Journal of the American Chemical Society, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 39 papers.
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Who cites it
39 citing papers in PubMed, 174 citations in OpenAlex.
- Verdazyl Radical Organocatalysis Overcomes Chain-Propagation Limitations in Borylation of Arenediazonium Salts.The Journal of organic chemistry · 2026Article
- Photochemical reduction of aryl chlorides, bromides, and iodidesChemical science · 2026Article
- Generation of a Ground-State Electron Donor Utilizing Stored Light Energy.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Regioselective Iodination of Arenes Using Iron- or Silver-Catalyzed Activation ofThe Journal of organic chemistry · 2026Article
- Shaking Up Photochemistry: The Future Frontiers of Mechanophotocatalysis.ACS central science · 2026Review
- Photocatalytic Aminoarylation of Styrenes.Organic letters · 2026Article
- Deazaalloxazines - Flavin Derivatives That Provide Reductive Photoredox Catalysis with Inert Substrates.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Dramatic expansion of bimodal redox window of indigo by two-electron redox processes.Nature communications · 2025Article
- Persistent Boryl Radicals as Highly Reducing Photoredox Catalysts for Debrominative Borylations.Journal of the American Chemical Society · 2025Article
- Photocatalytic Generation of a Ground-State Electron Donor Through Water Activation.Angewandte Chemie (International ed. in English) · 2025Article
- Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations.Chemical reviews · 2025Review
- Article
- Light-assisted functionalization of aryl radicals towards metal-free cross-coupling.Nature reviews. Chemistry · 2025Review
- A Computational Study of Photoinduced Borylation for Selected Boron Sources.ChemistryOpen · 2024Article
- Photoinduced Site-Selective Aryl C-H Borylation with Electron-Donor-Acceptor Complex Derived from BMolecules (Basel, Switzerland) · 2024Article
- Organophosphates as Versatile Substrates in Organic Synthesis.Molecules (Basel, Switzerland) · 2024Review
- AgNature communications · 2024Article
- Kinetic and thermodynamic control of C(spScience (New York, N.Y.) · 2023Article
- Organomediated electrochemical fluorosulfonylation of aryl triflates via selective C-O bond cleavage.Nature communications · 2023Article
- A Proton-Coupled Electron Transfer Strategy to the Redox-Neutral Photocatalytic COThe Journal of organic chemistry · 2023Article
Corrections and comments
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Authors and funding
9 authors at 2 institutions in 1 country.
Funding
Abstract
Boronic acids are centrally important functional motifs and synthetic precursors. Visible light-induced borylation may provide access to structurally diverse boronates, but a broadly efficient photocatalytic borylation method that can effect borylation of a wide range of substrates, including strong C-O bonds, remains elusive. Herein, we report a general, metal-free visible light-induced photocatalytic borylation platform that enables borylation of electron-rich derivatives of phenols and anilines, chloroarenes, as well as other haloarenes. The reaction exhibits excellent functional group tolerance, as demonstrated by the borylation of a range of structurally complex substrates. Remarkably, the reaction is catalyzed by phenothiazine, a simple organic photocatalyst with MW < 200 that mediates the previously unachievable visible light-induced single electron reduction of phenol derivatives with reduction potentials as negative as approximately - 3 V versus SCE by a proton-coupled electron transfer mechanism. Mechanistic studies point to the crucial role of the photocatalyst-base interaction.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.