ArticleiScience2020
Visible-Light-Induced Alkoxyl Radicals Enable α-C(sp
Article in iScience, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
- Activation of alcohols as sulfonium salts in the photocatalytic hetero-difunctionalization of alkenes.Nature chemistry · 2026Article
- Bioorthogonal Photocatalytic Protein Labeling and Cross-Linking Enabled by Stabilized Ketyl Radicals.Journal of the American Chemical Society · 2025Article
- Organophotoredox Dioxygenation of Alkenes via ROH···F-ActivatedOrganic letters · 2025Article
- Photocatalytic Partial Water Oxidation Promoted by a Hydrogen Acceptor-Hydroxyl Mediator Couple.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Photocatalytic 1,3-oxyheteroarylation of aryl cyclopropanes with azineChemical science · 2024Article
- Scavenging of Alkylperoxyl Radicals by Addition to Ascorbate: An Alternative Mechanism to Electron Transfer.Antioxidants (Basel, Switzerland) · 2024Article
- Direct Synthesis of 2-Hydroxytrifluoroethylacetophenones via Organophotoredox-Mediated Net-Neutral Radical/Polar Crossover.The Journal of organic chemistry · 2024Article
- Visible-Light-Mediated Ring-Opening Geminal Dibromination of Alkenes via Alkoxy Radicals Enabled by Electron Donor-Acceptor Complex.Molecules (Basel, Switzerland) · 2024Article
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- Net-1,2-Hydrogen Atom Transfer of Amidyl Radicals: Toward the Synthesis of 1,2-Diamine Derivatives.Journal of the American Chemical Society · 2023Article
- Direct Synthesis of α-Aryl-α-Trifluoromethyl Alcohols via Nickel Catalyzed Cross-Electrophile Coupling.Angewandte Chemie (International ed. in English) · 2022Article
- Radical Redox Annulations: A General Light-Driven Method for the Synthesis of Saturated Heterocycles.ACS catalysis · 2022Article
- Direct C-H Allylation of Unactivated Alkanes by Cooperative W/Cu Photocatalysis.Organic letters · 2022Article
- Solvent-controlled photocatalytic divergent cyclization of alkynyl aldehydes: access to cyclopentenones and dihydropyranols.Chemical science · 2021Article
- Tuning the reactivity of alkoxyl radicals from 1,5-hydrogen atom transfer to 1,2-silyl transfer.Nature communications · 2021Article
- Toward Rational Understandings of α-C-H Functionalization: Energetic Studies of Representative Tertiary Amines.iScience · 2020Article
Corrections and comments
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The alkoxyl radical is an essential reactive intermediate in mechanistic studies and organic synthesis with hydrogen atom transfer (HAT) reactivity. However, compared with intramolecular 1,5-HAT or intermolecular HAT of alkoxyl radicals, the intramolecular 1,2-HAT reactivity has been limited to theoretical studies and rarely synthetically utilized. Here we report the first selective 1,2-HAT of alkoxyl radicals for α-C(sp
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