Evidence map›Paper›PMID 31865572›Full record

ArticleEnvironmental science and pollution research international2020

Synthesis and application of Cu-BTC@ZSM-5 composites as effective adsorbents for removal of toluene gas under moist ambience: kinetics, thermodynamics, and mechanism studies.

Meng Li, Yuwei Li, Wei Li, Fang Liu, Xuejin Qi, Ming Xue, Yongqiang Wang, Chaocheng Zhao

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Article in Environmental science and pollution research international, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
0.7field-weighted citation impact, top 33% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed, 28 citations in OpenAlex.

  1. Nano-lamellar H-ZSM-5 molecular sieves for enhanced indoor air purification: Synthesis and adsorption characterization.Technology and health care : official journal of the European Society for Engineering and Medicine · 2024
    Article
  2. Review
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors at 2 institutions in 1 country.

Meng LiCollege of Chemical Engineering, China University of Petroleum, Qingdao, 266580, People's Republic of China.
Yuwei LiCollege of Chemical Engineering, China University of Petroleum, Qingdao, 266580, People's Republic of China.
Wei LiCollege of Chemical Engineering, China University of Petroleum, Qingdao, 266580, People's Republic of China.
Fang LiuCollege of Chemical Engineering, China University of Petroleum, Qingdao, 266580, People's Republic of China. liufangfw@163.com.ORCID http://orcid.org/0000-0001-6509-3701
Xuejin QiCollege of Chemical Engineering, China University of Petroleum, Qingdao, 266580, People's Republic of China.
Ming XueState Key Laboratory of Petroleum Pollution Control, Beijing, 102206, People's Republic of China.
Yongqiang WangCollege of Chemical Engineering, China University of Petroleum, Qingdao, 266580, People's Republic of China.
Chaocheng ZhaoCollege of Chemical Engineering, China University of Petroleum, Qingdao, 266580, People's Republic of China.
China University of Petroleum, East China · CNChina University of Petroleum, Beijing · CN

Funding

the Open Project Program of State Key Laboratory of Petroleum Pollution Control No. PPCIP2017005
6 · The paper itself

Abstract

Metal organic frameworks (MOFs) are excellent adsorbents that provide abundant specific surface area, adjustable pore structure, and rich active sites. The purpose of this study was to prepare composites with hydrophobic and high microporous specific surface area and to adsorb toluene gas in moist ambience. An ethanol activation-assisted hydrothermal method was proposed to synthesize copper-benzene-1,3,5-tricarboxylic acid (Cu-BTC) metal-organic framework, Cu-BTC, and ZSM-5 molecular sieve composites (Cu-BTC@ZSM-5). The dynamic adsorption process of toluene on different adsorbents was investigated, and the results showed that the toluene adsorption capacity of Cu-BTC@ZSM-5 (158.6 mg/g) was 2.53 times higher than Cu-BTC (62.7 mg/g), when the ZSM-5 content is 5% and the humidity is 30%RH. Compared with other factors, the humidity inhibited the adsorption of toluene on Cu-BTC@ZSM-5. Langmuir model and the pseudo-second kinetics model can better describe the adsorption behavior of Cu-BTC@ZSM-5. The thermodynamic results showed the adsorption process was a spontaneous exothermic process at low temperature and mainly physical adsorption. The relative regenerability can still up to 80.4% after six cycles. The adsorption mechanisms of Cu-BTC@ZSM-5 were pore-filling adsorption, π-π interaction, cation-π bonding, and hydrophobic interactions. This study will help to design a systematic route to evaluate the adsorption performance of Cu-BTC@ZSM-5 for toluene.

Indexed as

AdsorptionAir PollutantsBenzeneKineticsModels, ChemicalThermodynamicsTolueneAir PollutantsBenzeneTolueneAdsorption properties of tolueneCu-BTC@ZSM-5 compositeEthanol activation-hydrothermal methodMechanismMetal organic frameworks (MOFs)Volatile organic compounds (VOCs)

Identifiers

PMID31865572
OpenAlexW2996565744

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.