ArticleACS omega2019
Colloidal Palladium Nanoparticles for Selective Hydrogenation of Styrene Derivatives with Reactive Functional Groups.
Article in ACS omega, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Catalytic Activity of Incorporated Palladium Nanoparticles on Recycled Carbon Black from Scrap Tires.ACS omega · 2024Article
- Synthesis of Zinc Nanoparticles by the Gas Condensation Method in a Non-Contact Crucible and Their Physical-Chemical Characterization.Nanomaterials (Basel, Switzerland) · 2024Article
- Water-Soluble Pd Nanoparticles for the Anti-Markovnikov Oxidation of Allyl Benzene in Water.Nanomaterials (Basel, Switzerland) · 2023Article
- Effects of lipid bilayer encapsulation and lipid composition on the catalytic activity and colloidal stability of hydrophobic palladium nanoparticles in water.RSC advances · 2022Article
- Interlayer Coordination of Pd-Pd Units in Exfoliated Black Phosphorus.Journal of the American Chemical Society · 2021Article
- Water-Soluble Noble Metal Nanoparticle Catalysts Capped with Small Organic Molecules for Organic Transformations in Water.ACS applied nano materials · 2021Article
- Proximity Effects of Methyl Group on Ligand Steric Interactions and Colloidal Stability of Palladium Nanoparticles.Frontiers in chemistry · 2020Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
This article presents the catalysis investigation of octanethiolate-capped palladium nanoparticles (C8 PdNP) and phenylethanethiolate-capped palladium nanoparticles (PhC2 PdNP) for chemoselective catalytic hydrogenation reactions of styrene derivatives in the presence of other reducible functionalities. The results show that the C8 PdNP is highly active under mild reaction conditions (room temperature and atmospheric pressure) and selective for hydrogenating monosubstituted alkene groups without reducing other reactive functional groups such as nitro, halo, carbonyls, and so forth. In comparison, the noncovalent interactions between surface phenyl ligands and aromatic substrates are found to hinder the hydrogenation activity of PhC2 PdNP.
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Registered trials
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