ArticleChemical science2019
Solid-state Suzuki-Miyaura cross-coupling reactions: olefin-accelerated C-C coupling using mechanochemistry.
Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 31 papers.
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Who cites it
31 citing papers in PubMed.
- Mechanochemical generation of chlorine dioxide radical for solvent-free oxygenation of dibenzothiophenes.RSC advances · 2026Article
- Developing efficient mechanochemical routes to porous metal-organic polyhedra, supported by 3D electron diffraction.Chemical science · 2026Article
- Shaking Up Photochemistry: The Future Frontiers of Mechanophotocatalysis.ACS central science · 2026Review
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- Mechanochemical Strategies Applied to the Late-Stage Modifications of Pharmaceutically Active Compounds.Angewandte Chemie (International ed. in English) · 2025Review
- A cooperative electron-deficient phosphine/olefin ligand system for the site-selective mechanochemical Suzuki-Miyaura cross-coupling of 2,4-dibromoaryl ethers.Chemical science · 2025Article
- Mechanochemical Synthesis of Advanced Materials for All-Solid-State Battery (ASSB) Applications: A Review.Polymers · 2025Review
- Immobilization of Palladium(II)acetate complex on dendrimer functionalized Cobalt ferrite nanoparticles as a nanocatalyst for Suzuki-Miyaura coupling and oxidation of sulfide.Scientific reports · 2025Article
- Solventless Catalytic C-H and C-X Functionalization without Ball Milling.The Journal of organic chemistry · 2025Article
- Thermally accelerated Heck reaction under direct mechanocatalysis using palladium milling balls.RSC mechanochemistry · 2025Article
- A facile plant and chemical-mediated mechanosynthesis of α-FeRSC advances · 2025Article
- Mechanochemical Sequential Deoxygenative Cross-Coupling Reactions of Phenols Under Ruthenium-Nickel Catalysis.Molecules (Basel, Switzerland) · 2025Article
- Synthesis of Core-Functionalised Naphthalenediimides from Naphthalenetetracarboxylic Dianhydride using a Vibratory Ball Mill: Bromination, Imidization and Heck-Type Reactions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Mechanochemistry for Organic and Inorganic Synthesis.ACS organic & inorganic Au · 2024Review
- Allylation ofAngewandte Chemie (Weinheim an der Bergstrasse, Germany) · 2024Article
- Allylation of C-, N-, and O-Nucleophiles via a Mechanochemically-Driven Tsuji-Trost Reaction Suitable for Late-Stage Modification of Bioactive Molecules.Angewandte Chemie (International ed. in English) · 2024Article
- Mechanochemical Synthesis of PdOMolecules (Basel, Switzerland) · 2023Article
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The Suzuki-Miyaura cross-coupling reaction is one of the most reliable methods for the construction of carbon-carbon bonds in solution. However, examples for the corresponding solid-state cross-coupling reactions remain scarce. Herein, we report the first broadly applicable mechanochemical protocol for a solid-state palladium-catalyzed organoboron cross-coupling reaction using an olefin additive. Compared to previous studies, the newly developed protocol shows a substantially broadened substrate scope. Our mechanistic data suggest that olefin additives might act as dispersants for the palladium-based catalyst to suppress higher aggregation of the nanoparticles, and also as stabilizer for the active monomeric Pd(0) species, thus facilitating these challenging solid-state C-C bond forming cross-coupling reactions.
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