ArticleJournal of the American Chemical Society2020
Ligand Redox Noninnocence in [Co
Article in Journal of the American Chemical Society, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 27 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
27 citing papers in PubMed, 90 citations in OpenAlex.
- Nitrene-Transfer Chemistry to Olefins Mediated by Co(III) Catalysts Supported by a Tetraamido Macrocycle.Inorganic chemistry · 2026Article
- A Mononuclear Ruthenium(V)-Imido Complex With Hydrogen Bonding in the Second Coordination Sphere Forming Aziridines Without N-Substituents From Alkenes in Water.Angewandte Chemie (International ed. in English) · 2026Article
- Nitrogen Subvalency in a Four-Member Redox Series of Iron-Sulfur Cluster Imido Complexes.Journal of the American Chemical Society · 2025Article
- Natural Amino Acid-Derived Iron(III) Catalysts for Green Oxidation Chemistry Applications.ACS omega · 2025Article
- Synthesis and Characterization of Co Complexes Coordinated by a Tetraanionic Bis(amidateanilido) Ligand.Inorganic chemistry · 2025Article
- Synthesis, Structure, and Redox Reactivity of Ni Complexes Bearing a Redox and Acid-Base Non-innocent Ligand with NiJournal of the American Chemical Society · 2025Article
- Identification, Characterization, and Electronic Structures of Interconvertible Cobalt-Oxygen TAML Intermediates.Journal of the American Chemical Society · 2024Article
- Article
- Nitrogen atom insertion into arenols to access benzazepines.Chemical science · 2024Article
- Peculiar Differences between Two Copper Complexes Containing Similar Redox-Active Ligands: Density Functional and Multiconfigurational Calculations.Inorganic chemistry · 2024Article
- Isomerization pathway of a C-C sigma bond in a bis(octaazamacrocycle)dinickel(II) complex activated by deprotonation: a DFT study.Theoretical chemistry accounts · 2024Article
- Generation, Spectroscopic Characterization, and Computational Analysis of a Six-Coordinate Cobalt(III)-Imidyl Complex with an UnusualJournal of the American Chemical Society · 2023Article
- Ruthenium(v) terminal arylimido corroles: isolation, spectroscopic characterization and reactivity.Chemical science · 2023Article
- Interplay and Competition Between Two Different Types of Redox-Active Ligands in Cobalt Complexes: How to Allocate the Electrons?Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Umpolung in a Pair of Cobalt(III) Terminal Imido/Imidyl Complexes.Angewandte Chemie (International ed. in English) · 2022Article
- Cooperative B-H bond activation: dual site borane activation by redox active κChemical science · 2022Article
- Cobalt(II)-tetraphenylporphyrin-catalysed carbene transfer from acceptor-acceptor iodonium ylides via N-enolate-carbene radicals.Nature chemistry · 2022Article
- Diastereomeric dinickel(II) complexes with non-innocent bis(octaazamacrocyclic) ligands: isomerization, spectroelectrochemistry, DFT calculations and use in catalytic oxidation of cyclohexane.Dalton transactions (Cambridge, England : 2003) · 2022Article
- A DMRG/CASPT2 Investigation of Metallocorroles: Quantifying Ligand Noninnocence in Archetypal 3d and 4d Element Derivatives.JACS Au · 2021Article
- Controlling Radical-Type Single-Electron Elementary Steps in Catalysis with Redox-Active Ligands and Substrates.JACS Au · 2021Review
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
9 authors at 2 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The redox noninnocence of the TAML scaffold in cobalt-TAML (tetra-amido macrocyclic ligand) complexes has been under debate since 2006. In this work, we demonstrate with a variety of spectroscopic measurements that the TAML backbone in the anionic complex
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.