Evidence map›Paper›PMID 31846109›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2020

A Comprehensive Study on Tetraaryltetrabenzoporphyrins.

Michael Ruppel, Dominik Lungerich, Sabrina Sturm, Rainer Lippert, Frank Hampel, Norbert Jux

Abstract read
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.

0numbers the graph read from it
0cells of the map it votes in
9citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

9 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Synthesis of NovelACS omega · 2025
    Article
  5. Synthesis and Evaluation of NovelACS medicinal chemistry letters · 2024
    Article
  6. Article
  7. Nucleophilic Aromatic Substitution (SEuropean journal of organic chemistry · 2021
    Review
  8. Article
  9. A Comprehensive Study on Tetraaryltetrabenzoporphyrins.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Michael RuppelDepartment of Chemistry and Pharmacy & Interdisciplinary Center for, Molecular Materials (ICMM), Organic Chemistry II, Friedrich-Alexander University Erlangen-Nuernberg, Nikolaus-Fiebiger-Str. 10, 91058, Erlangen, Germany.ORCID http://orcid.org/0000-0001-6474-5106
Dominik LungerichDepartment of Chemistry and Pharmacy & Interdisciplinary Center for, Molecular Materials (ICMM), Organic Chemistry II, Friedrich-Alexander University Erlangen-Nuernberg, Nikolaus-Fiebiger-Str. 10, 91058, Erlangen, Germany.ORCID http://orcid.org/0000-0002-3093-3624
Sabrina SturmDepartment of Chemistry and Pharmacy, Bioinorganic Chemistry, Friedrich-Alexander University Erlangen-Nuernberg, Egerlandstr. 1, 91058, Erlangen, Germany.
Rainer LippertDepartment of Chemistry and Pharmacy, Bioinorganic Chemistry, Friedrich-Alexander University Erlangen-Nuernberg, Egerlandstr. 1, 91058, Erlangen, Germany.
Frank HampelDepartment of Chemistry and Pharmacy & Interdisciplinary Center for, Molecular Materials (ICMM), Organic Chemistry II, Friedrich-Alexander University Erlangen-Nuernberg, Nikolaus-Fiebiger-Str. 10, 91058, Erlangen, Germany.ORCID http://orcid.org/0000-0001-9768-782X
Norbert JuxDepartment of Chemistry and Pharmacy & Interdisciplinary Center for, Molecular Materials (ICMM), Organic Chemistry II, Friedrich-Alexander University Erlangen-Nuernberg, Nikolaus-Fiebiger-Str. 10, 91058, Erlangen, Germany.ORCID http://orcid.org/0000-0002-5673-8181

Funding

Deutsche Forschungsgemeinschaft 182849149
6 · The paper itself

Abstract

Tetraaryltetrabenzoporphyrins (TATBPs) show, due to their optoelectronic properties, rising potential as dyes in various fields of physical and biomedical sciences. However, unlike in the case of porphyrins, the potential structural diversity of TATBPs has been explored only to little extent, owed mainly to synthetic hurdles. Herein, we prepared a comprehensive library of 30 TATBPs and investigated their fundamental properties. We elucidated structural properties by X-ray crystallography and found explanations for physical properties such as solubility. Fundamental electronic aspects were studied by optical spectroscopy as well as by electrochemistry and brought in context to the stability of the molecules. Finally, we were able to develop a universal synthetic protocol, utilizing a readily established isoindole synthon, which gives TATBPs in high yields, regardless of the nature of the used arylaldehyde and without meticulous chromatographic purifications steps. This work serves as point of orientation for scientists, that aim to utilize these molecules in materials, nanotechnological, and biomedical applications.

Indexed as

crystal engineeringelectrochemistryphotochemistryporphyrinoidsUV/Vis spectroscopy

Identifiers

PMID31846109
PMCPMC7154557

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.