Deoxydehydration of vicinal diols by homogeneous catalysts: a mechanistic overview.

Open access · goldAbstract readReview

In one paragraph

Review in Royal Society open science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it

0cells of the map it votes in

1citing papers in PubMed

1.4field-weighted citation impact, top 20% of its field

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 27 citations in OpenAlex.

Direct Deoxydehydration of Cyclic trans-Diol Substrates: An Experimental and Computational Study of the Reaction Mechanism of Vanadium(V)-based Catalysis*.ChemSusChem · 2021
Article

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors at 1 institution in 1 country.

Kayla A DeNikeDepartment of Chemistry and Biochemistry, University of Arkansas, 1 University of Arkansas, Fayetteville, AR 727001, USA.

Stefan M KilyanekDepartment of Chemistry and Biochemistry, University of Arkansas, 1 University of Arkansas, Fayetteville, AR 727001, USA.ORCID 0000-0002-6179-2510

University of Arkansas at Fayetteville · US

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Deoxydehydration (DODH) is an important reaction for the upconversion of biomass-derived polyols to commodity chemicals such as alkenes and dienes. DODH can be performed by a variety of early metal-oxo catalysts incorporating Re, Mo and V. The varying reduction methods used in the DODH catalytic cycle impact the product distribution, reaction mechanism and the overall yield of the reaction. This review surveys the reduction methods commonly used in homogeneous DODH catalyst systems and their impacts on yield and reaction conditions.

Indexed as

biomass upconversioncatalysisdeoxydehydrationearly metal-oxo

Identifiers

PMID31827851

DOI10.1098/rsos.191165

PMCPMC6894556

OpenAlexW2989469709

What OpenQuestion holds

Textmetadata

LicenceCC BY

Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.