ArticleNature communications2019
Vibronic coherence evolution in multidimensional ultrafast photochemical processes.
Article in Nature communications, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
- Vibronic Coherence in a Minimal Pigment-Protein Complex Probed by Two-Dimensional Electronic-Vibrational Spectroscopy.The journal of physical chemistry. B · 2026Article
- Solvent Polarity as a Diagnostic for Vibronic/Vibrational Coherences Distinction in an Efficient TADF-TTA Switchable Emitter.Small science · 2026Article
- Quantum-Indeterminate Proton Positions in Ultrafast Excited-State Intramolecular Proton Transfer.The journal of physical chemistry letters · 2026Article
- Tracking coherent vibronic and vibrational motions in ultrafast proton transfer.Nature communications · 2026Article
- Jahn-Teller distortion controls electron transfer in photoexcited Cu(i) donor-acceptor systems.Chemical science · 2026Article
- Capturing coherent pseudorotation through conical intersection in photoionized benzene.Nature communications · 2025Article
- A numerically exact description of ultrafast vibrational decoherence in vibration-coupled electron transfer.Proceedings of the National Academy of Sciences of the United States of America · 2025Article
- A Cost-Effective Computational Strategy for the Electronic Layout Characterization of a Second Generation Light-Driven Molecular Rotary Motor in Solution.Journal of computational chemistry · 2025Article
- Robust vibrational coherence protected by a core-shell structure in silver nanoclusters.Chemical science · 2024Article
- Watching the Interplay between Photoinduced Ultrafast Charge Dynamics and Nuclear Vibrations.Journal of chemical theory and computation · 2023Article
- Energy transfer in N-component nanosystems enhanced by pulse-driven vibronic many-body entanglement.Scientific reports · 2023Article
- Article
- Accelerating symmetry-breaking charge separation in a perylenediimide trimer through a vibronically coherent dimer intermediate.Nature chemistry · 2022Article
- Theoretical approach to modeling the early nonadiabatic events of ESIPT originating from three-state conical intersection in quinophthalone.Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology · 2022Article
- Hidden vibronic and excitonic structure and vibronic coherence transfer in the bacterial reaction center.Science advances · 2022Article
- Two-dimensional electronic-vibrational sum frequency spectroscopy for interactions of electronic and nuclear motions at interfaces.Proceedings of the National Academy of Sciences of the United States of America · 2021Article
- The role of mixed vibronic QNature communications · 2020Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The complex choreography of electronic, vibrational, and vibronic couplings used by photoexcited molecules to transfer energy efficiently is remarkable, but an unambiguous description of the temporally evolving vibronic states governing these processes has proven experimentally elusive. We use multidimensional electronic-vibrational spectroscopy to identify specific time-dependent excited state vibronic couplings involving multiple electronic states, high-frequency vibrations, and low-frequency vibrations which participate in ultrafast intersystem crossing and subsequent relaxation of a photoexcited transition metal complex. We discover an excited state vibronic mechanism driving long-lived charge separation consisting of an initial electronically-localized vibrational wavepacket which triggers delocalization onto two charge transfer states after propagating for ~600 femtoseconds. Electronic delocalization consequently occurs through nonadiabatic internal conversion driven by a 50 cm
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.