ArticleScience advances2019
Manipulating optical nonlinearities of molecular polaritons by delocalization.
Article in Science advances, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
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Who cites it
19 citing papers in PubMed.
- Ultrafast Dynamics of Organic Exciton-Polaritons.Nanophotonics (Berlin, Germany) · 2026Article
- Excited State Dynamics of COJournal of the American Chemical Society · 2025Article
- Vibrational weak and strong coupling modify a chemical reaction via cavity-mediated radiative energy transfer.Nature chemistry · 2025Article
- Spatially Resolved Near Field Spectroscopy of Vibrational Polaritons at the Small N Limit.ACS photonics · 2024Article
- Probing the anharmonicity of vibrational polaritons with double-quantum two-dimensional infrared spectroscopy.Nanophotonics (Berlin, Germany) · 2024Article
- A 2D chiral microcavity based on apparent circular dichroism.Nature communications · 2024Article
- Ultrafast Spectroscopy under Vibrational Strong Coupling in Diphenylphosphoryl Azide.The journal of physical chemistry. A · 2024Article
- Molecular Polaritons for Chemistry, Photonics and Quantum Technologies.Chemical reviews · 2024Review
- Molecular Vibrational Polariton Dynamics: What Can Polaritons Do?Accounts of chemical research · 2023Article
- Enabling multiple intercavity polariton coherences by adding quantum confinement to cavity molecular polaritons.Proceedings of the National Academy of Sciences of the United States of America · 2023Article
- Molecular polariton electroabsorption.Nature communications · 2022Article
- Energy cascades in donor-acceptor exciton-polaritons observed by ultrafast two-dimensional white-light spectroscopy.Nature communications · 2022Article
- Multimode polariton effects on molecular energy transport and spectral fluctuations.Communications chemistry · 2022Article
- Nonlinear infrared polaritonic interaction between cavities mediated by molecular vibrations at ultrafast time scale.Science advances · 2021Article
- Complex plasmon-exciton dynamics revealed through quantum dot light emission in a nanocavity.Nature communications · 2021Article
- Enhancing Vibrational Light-Matter Coupling Strength beyond the Molecular Concentration Limit Using Plasmonic Arrays.Nano letters · 2021Article
- Excited-state vibration-polariton transitions and dynamics in nitroprusside.Nature communications · 2021Article
- Polaritons and excitons: Hamiltonian design for enhanced coherence.Proceedings. Mathematical, physical, and engineering sciences · 2020Article
- Polariton Transitions in Femtosecond Transient Absorption Studies of Ultrastrong Light-Molecule Coupling.The journal of physical chemistry letters · 2020Article
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Optical nonlinearities are key resources in the contemporary photonics toolbox, relevant to quantum gate operations and all-optical switches. Chemical modification is often used to control the nonlinear response of materials at the microscopic level, but on-the-fly manipulation of such response is challenging. Tunability of optical nonlinearities in the mid-infrared (IR) is even less developed, hindering its applications in chemical sensing or IR photonic circuitry. Here, we report control of vibrational polariton coherent nonlinearities by manipulation of macroscopic parameters such as cavity longitudinal length or molecular concentration. Further two-dimensional IR investigations reveal that nonlinear dephasing provides the dominant source of the observed ultrafast polariton nonlinearities. The reported phenomena originate from the nonlinear macroscopic polarization stemming from strong coupling between microscopic molecular excitations and a macroscopic photonic cavity mode.
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