ArticleChemistry (Weinheim an der Bergstrasse, Germany)2020
α-Imino Gold Carbene Intermediates from Readily Accessible Sulfilimines: Intermolecular Access to Structural Diversity.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- Photo-induced selective N-N bond construction via harnessing nitrene release and transfer.Nature communications · 2026Article
- Chemo- and Regioselective Synthesis of 3,4-Dihydropyrimidin-4-ones from 4,5-Dihydro-1,2,4-oxadiazoles and Chromium Alkoxy Alkynyl Fischer Carbene Complexes.Organic letters · 2025Article
- Review
- Gold-Catalyzed Cyclization of Yndiamides with Isoxazoles via α-Imino Gold Fischer Carbenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Article
- An unexpected synthesis of azepinone derivatives through a metal-free photochemical cascade reaction.Nature communications · 2023Article
- Bifunctional sulfilimines enable synthesis of multiple N-heterocycles from alkenes.Nature chemistry · 2022Article
- Biomolecule-Compatible Dehydrogenative Chan-Lam Coupling of Free Sulfilimines.Journal of the American Chemical Society · 2022Article
- Anodic Dehydrogenative Cyanamidation of Thioethers: Simple and Sustainable Synthesis of N-Cyanosulfilimines.Angewandte Chemie (International ed. in English) · 2021Article
- Gold-Catalyzed Synthesis of Small Rings.Chemical reviews · 2021Article
- Copper-catalyzed asymmetric cyclization of alkenyl diynes: method development and new mechanistic insights.Chemical science · 2021Article
- Au-Ag Bimetallic Catalysis: 3-Alkynyl Benzofurans from Phenols via Tandem C-H Alkynylation/Oxy-Alkynylation.Angewandte Chemie (International ed. in English) · 2021Article
- Synthesis of Carbazoles and Related Heterocycles from Sulfilimines by Intramolecular C-H Aminations.Angewandte Chemie (International ed. in English) · 2020Article
- Dibenzothiophenesulfilimines: A Convenient Approach to Intermolecular Rhodium-Catalysed C-H Amidation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- α-Imino Gold Carbene Intermediates from Readily Accessible Sulfilimines: Intermolecular Access to Structural Diversity.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
Catalytic approaches to pharmaceutically important bioactive skeletons through gold carbene intermediates have experienced a dramatic development in the last decade. Although various carbene precursors continue to play an important role in heterocyclic syntheses, these reagents are associated with some drawbacks in terms of functional group tolerance, synthetic methods and safety limitations. A new generation of nitrene transfer reagents was established in 2019: the sulfilimines. These are safe, inexpensive and readily available. They can conveniently be stored and handled, and thus represent ideal reagents for the fast and modular modification of scaffolds and the preparation of libraries by intermolecular reactions of two components. Both the practical methods for synthesizing sulfilimines and the versatility of these ylidic species in gold-catalyzed preparation of structural diversity, for both heterocycles and carbocycles, will be outlined in this Concept article.
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