ArticleAngewandte Chemie (International ed. in English)2020
Electrochemical Access to Aza-Polycyclic Aromatic Hydrocarbons: Rhoda-Electrocatalyzed Domino Alkyne Annulations.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed.
- Cathodic oxygen reduction-enabled rhodium-catalyzed (5 + 1) C-H/O-H annulation inspired by fuel cells.Nature communications · 2025Article
- Green advancements towards the electrochemical synthesis of heterocycles.RSC advances · 2024Review
- Bifurcated Rhodaelectro-catalyzed C-H Activation for the Synthesis of Pyrroles and Lactones.Precision chemistry · 2023Article
- Heterocyclic Electrochemistry: Renewable Electricity in the Construction of Heterocycles.ACS omega · 2023Review
- Rhodaelectro-Catalyzed peri-Selective Direct Alkenylations with Weak O-Coordination Enabled by the Hydrogen Evolution Reaction (HER).Angewandte Chemie (International ed. in English) · 2022Article
- Rapid access to polycyclic N-heteroarenes from unactivated, simple azines via a base-promoted Minisci-type annulation.Nature communications · 2022Article
- Computational, Mechanistic, and Experimental Insights into Regioselective Catalytic C-C Bond Activation in Linear 1-Aza-[3]triphenylene.ACS omega · 2022Article
- Advances on the Merger of Electrochemistry and Transition Metal Catalysis for Organic Synthesis.Chemical reviews · 2022Review
- Electrochemical organic reactions: A tutorial review.Frontiers in chemistry · 2022Review
- Organic Electrochemistry: Molecular Syntheses with Potential.ACS central science · 2021Review
- Harnessing sulfur and nitrogen in the cobalt(iii)-catalyzed unsymmetrical double annulation of thioamides: probing the origin of chemo- and regio-selectivity.Chemical science · 2021Article
- Ruthenaelectro-Catalyzed Domino Three-Component Alkyne Annulation for Expedient Isoquinoline Assembly.Angewandte Chemie (International ed. in English) · 2021Article
- Divergent rhodium-catalyzed electrochemical vinylic C-H annulation of acrylamides with alkynes.Nature communications · 2021Article
- Enantioselective Pallada-Electrocatalyzed C-H Activation by Transient Directing Groups: Expedient Access to Helicenes.Angewandte Chemie (International ed. in English) · 2020Article
- Renewable resources for sustainable metallaelectro-catalysed C-H activation.Chemical science · 2020Review
- Electrochemical Access to Aza-Polycyclic Aromatic Hydrocarbons: Rhoda-Electrocatalyzed Domino Alkyne Annulations.Angewandte Chemie (International ed. in English) · 2020Article
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Authors and funding
4 authors.
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Abstract
Nitrogen-doped polycyclic aromatic hydrocarbons (aza-PAHs) have found broad applications in material sciences. Herein, a modular electrochemical synthesis of aza-PAHs was developed via a rhodium-catalyzed cascade C-H activation and alkyne annulation. A multifunctional O-methylamidoxime enabled the high chemo- and regioselectivity. The isolation of two key rhodacyclic intermediates made it possible to delineate the exact order of three C-H activation steps. In addition, the metalla-electrocatalyzed multiple C-H transformation is characterized by unique functional group tolerance, including highly reactive iodo and azido groups.
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