Rapid Entry into Biologically Relevant α,α-Difluoroalkylphosphonates Bearing Allyl Protection-Deblocking under Ru(II)/(IV)-Catalysis.

Kaushik Panigrahi, Xiang Fei, Masato Kitamura, David B Berkowitz

Open access · greenAbstract read

In one paragraph

Article in Organic letters, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it

0cells of the map it votes in

2citing papers in PubMed

0.7field-weighted citation impact, top 37% of its field

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed, 10 citations in OpenAlex.

Iodine(V)-Based Oxidants in Oxidation Reactions.Molecules (Basel, Switzerland) · 2023
Review
A Hammett Study of Clostridium acetobutylicum Alcohol Dehydrogenase (CaADH): An Enzyme with Remarkable Substrate Promiscuity and Utility for Organic Synthesis.Synlett : accounts and rapid communications in synthetic organic chemistry · 2020
Article

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 2 institutions in 2 countries.

Kaushik PanigrahiDepartment of Chemistry , University of Nebraska , Lincoln , Nebraska 68588-0304 , United States.

Xiang FeiDepartment of Chemistry , University of Nebraska , Lincoln , Nebraska 68588-0304 , United States.

Masato KitamuraGraduate School of Pharmaceutical Sciences , Nagoya University , Furo-cho, Chikusa-ku, Nagoya 464-8602 , Japan.ORCID 0000-0002-0543-8795

David B BerkowitzDepartment of Chemistry , University of Nebraska , Lincoln , Nebraska 68588-0304 , United States.ORCID 0000-0001-7550-0112

University of Nebraska–Lincoln · USNagoya University · JP

Funding

EXTRAMURAL RES FACILITIES CONSTRC06RR016544 · NCRR · UNIVERSITY OF NEBRASKA LINCOLN · PI PAUL, PREM S · 2001 to 2001

$2.0M

NCRR NIH HHS C06 RR016544

6 · The paper itself

Abstract

A convenient synthetic route to α,α-difluoroalkylphosphonates is described. Structurally diverse aldehydes are condensed with LiF

Indexed as

Allyl CompoundsCatalysisHumansHydrocarbons, FluorinatedMolecular StructureOrganophosphonatesProtein Tyrosine Phosphatase, Non-Receptor Type 1RutheniumAllyl CompoundsHydrocarbons, FluorinatedOrganophosphonatesProtein Tyrosine Phosphatase, Non-Receptor Type 1PTPN1 protein, humanRuthenium

Identifiers

PMID31789041

DOI10.1021/acs.orglett.9b03707

PMCPMC12084027

OpenAlexW2990004014

What OpenQuestion holds

Textmetadata

LicenceTDM

Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.