ArticleAngewandte Chemie (International ed. in English)2020
Dynamic Complex-to-Complex Transformations of Heterobimetallic Systems Influence the Cage Structure or Spin State of Iron(II) Ions.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
16 citing papers in PubMed.
- One Coordination Cage, Many Pathways: Multiple Stimuli Drive Reversible Transformations.JACS Au · 2026Article
- Interplay of Stereochemistry and Charge Governs Guest Binding in Flexible ZnJournal of the American Chemical Society · 2024Article
- PdChemical science · 2023Article
- Anionic Templates Drive Conversion between a ZnJournal of the American Chemical Society · 2023Article
- Subcomponent self-assembly of circular helical DyChemical science · 2022Article
- Adaptive coordination assemblies based on a flexible tetraazacyclododecane ligand for promoting carbon dioxide fixation.Chemical science · 2022Article
- Transformation networks of metal-organic cages controlled by chemical stimuli.Chemical Society reviews · 2022Review
- Beyond Platonic: How to Build Metal-Organic Polyhedra Capable of Binding Low-Symmetry, Information-Rich Molecular Cargoes.Chemical reviews · 2022Review
- Visible-Light Switching of Metallosupramolecular Assemblies.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Increasing structural and functional complexity in self-assembled coordination cages.Chemical science · 2021Review
- Multi-functional, Low Symmetry PdChemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Better Together: Functional Heterobimetallic Macrocyclic and Cage-like Assemblies.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Review
- A Paramagnetic NMR Spectroscopy Toolbox for the Characterisation of Paramagnetic/Spin-Crossover Coordination Complexes and Metal-Organic Cages.Angewandte Chemie (International ed. in English) · 2020Article
- Transformation Network Culminating in a Heteroleptic CdJournal of the American Chemical Society · 2020Article
- Dynamic Complex-to-Complex Transformations of Heterobimetallic Systems Influence the Cage Structure or Spin State of Iron(II) Ions.Angewandte Chemie (International ed. in English) · 2020Article
- A heterobimetallic tetrahedron from a linear platinum(II)-bis(acetylide) metalloligand.Beilstein journal of organic chemistry · 2020Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
9 authors.
Funding
Abstract
Two new heterobimetallic cages, a trigonal-bipyramidal and a cubic one, were assembled from the same mononuclear metalloligand by adopting the molecular library approach, using iron(II) and palladium(II) building blocks. The ligand system was designed to readily assemble through subcomponent self-assembly. It allowed the introduction of steric strain at the iron(II) centres, which stabilizes its paramagnetic high-spin state. This steric strain was utilized to drive dynamic complex-to-complex transformations with both the metalloligand and heterobimetallic cages. Addition of sterically less crowded subcomponents as a chemical stimulus transformed all complexes to their previously reported low-spin analogues. The metalloligand and bipyramid incorporated the new building block more readily than the cubic cage, probably because the geometric structure of the sterically crowded metalloligand favours the cube formation. Furthermore it was possible to provoke structural transformations upon addition of more favourable chelating ligands, converting the cubic structures into bipyramidal ones.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.