ArticleNature communications2019
Electrochemical oxidation induced intermolecular aromatic C-H imidation.
Article in Nature communications, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed, 108 citations in OpenAlex.
- Photochemical, electrochemical and electrophotochemical C-N bond-forming cross-coupling reactions.Nature reviews. Chemistry · 2026Review
- Electrochemical oxidation enables aromatic C-H amination with dual mechanisms.Nature synthesis · 2026Article
- Electrochemical Non-Directed Arene C-H Amination.ChemCatChem · 2024Article
- Site-Selective Electrochemical Arene C-H Amination.Journal of the American Chemical Society · 2024Article
- A review of recent advances in electrochemical and photoelectrochemical late-stage functionalization classified by anodic oxidation, cathodic reduction, and paired electrolysis.Beilstein journal of organic chemistry · 2024Review
- Electrochemical Late-Stage Functionalization.Chemical reviews · 2023Review
- Recent advances in the electrochemical reactions of nitrogen-containing organic compounds.RSC advances · 2022Review
- 1,2-Amino oxygenation of alkenes with hydrogen evolution reaction.Nature communications · 2022Article
- Photochemical and Electrochemical Applications of Proton-Coupled Electron Transfer in Organic Synthesis.Chemical reviews · 2022Review
- Insertion of ammonia into alkenes to build aromatic N-heterocycles.Nature communications · 2022Article
- Electrochemical organic reactions: A tutorial review.Frontiers in chemistry · 2022Review
- Electrochemical Dehydrogenative C(spChemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Direct amidation of metallaaromatics: access toChemical science · 2021Article
- Electrochemical C-H Amidation of Heteroarenes with N-Alkyl Sulfonamides in Aqueous Medium.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
Corrections and comments
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Authors and funding
5 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The dehydrogenative aryl C-H/N-H cross-coupling is a powerful synthetic methodology to install nitrogen functionalities into aromatic compounds. Herein, we report an electrochemical oxidation induced intermolecular cross-coupling between aromatics and sulfonimides with high regioselectivity through N-radical addition pathway under external-oxidant-free and catalyst-free conditions. A wide variety of arenes, heteroarenes, alkenes and sulfonimides are applicable scaffolds in this transformation. In addition, aryl sulfonamides or amines (aniline derivatives) can be obtained through different deprotection process. The cyclic voltammetry mechanistic study indicates that the N-centered imidyl radicals are generated via proton-coupled electron transfer event jointly mediated by tetrabutylammonium acetate and anode oxidation process.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.