ArticleAngewandte Chemie (International ed. in English)2020
C-H Oxygenation Reactions Enabled by Dual Catalysis with Electrogenerated Hypervalent Iodine Species and Ruthenium Complexes.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 26 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
26 citing papers in PubMed.
- Hydrogen-Bond-Assisted Hydroxylation ofMolecules (Basel, Switzerland) · 2026Article
- Electrochemical Enantioselective Ruthenium(II)-Catalyzed C-H Activations to Atropostable Indoles and Chiral Spiropyrazolones.Journal of the American Chemical Society · 2026Article
- Controlling Reductive Elimination Pathways in Ti(IV) Pincer Complexes: Concerted versus Radical Mechanisms via Ligand Design.Journal of the American Chemical Society · 2026Article
- Multisite Proton-Coupled Electron Transfer Enables Iodanyl Radical Catalysis.Journal of the American Chemical Society · 2025Article
- Unlocking Catalysis Using Oxidatively Induced Reductive Elimination.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Review
- Electrochemical Late-Stage Functionalization.Chemical reviews · 2023Review
- Concise Total Syntheses of the 6-7-5 Hamigeran Natural Products.Journal of the American Chemical Society · 2023Article
- C(spJournal of the American Chemical Society · 2023Article
- Toward a General Protocol for Catalytic Oxidative Transformations Using Electrochemically Generated Hypervalent Iodine Species.The Journal of organic chemistry · 2023Article
- Two-step continuous-flow synthesis of 6-membered cyclic iodonium salts via anodic oxidation.Beilstein journal of organic chemistry · 2023Article
- Iodine-Iodine Cooperation Enables Metal-Free C-N Bond-Forming Electrocatalysis via Isolable Iodanyl Radicals.Journal of the American Chemical Society · 2022Article
- Electrochemical aromatic C-H hydroxylation in continuous flow.Nature communications · 2022Article
- Rhodaelectro-Catalyzed peri-Selective Direct Alkenylations with Weak O-Coordination Enabled by the Hydrogen Evolution Reaction (HER).Angewandte Chemie (International ed. in English) · 2022Article
- Advances on the Merger of Electrochemistry and Transition Metal Catalysis for Organic Synthesis.Chemical reviews · 2022Review
- Recent Updates on Electrogenerated Hypervalent Iodine Derivatives and Their Applications as Mediators in Organic Electrosynthesis.Frontiers in chemistry · 2022Review
- Decarboxylative Hydroxylation of Benzoic Acids.Angewandte Chemie (International ed. in English) · 2021Article
- Electrochemical Generation of Hypervalent Bromine(III) Compounds.Angewandte Chemie (International ed. in English) · 2021Article
- Rhoda-Electrocatalyzed Bimetallic C-H Oxygenation by Weak O-Coordination.Angewandte Chemie (International ed. in English) · 2021Article
- Organic Electrochemistry: Molecular Syntheses with Potential.ACS central science · 2021Review
- Ruthenaelectro-Catalyzed Domino Three-Component Alkyne Annulation for Expedient Isoquinoline Assembly.Angewandte Chemie (International ed. in English) · 2021Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
6 authors.
Funding
Abstract
The catalytic generation of hypervalent iodine(III) reagents by anodic electrooxidation was orchestrated towards an unprecedented electrocatalytic C-H oxygenation of weakly coordinating aromatic amides and ketones. Thus, catalytic quantities of iodoarenes in concert with catalytic amounts of ruthenium(II) complexes set the stage for versatile C-H activations with ample scope and high functional group tolerance. Detailed mechanistic studies by experiment and computation substantiate the role of the iodoarene as the electrochemically relevant species towards C-H oxygenations with electricity as a sustainable oxidant and molecular hydrogen as the sole by-product. para-Selective C-H oxygenations likewise proved viable in the absence of directing groups.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.