Evidence map›Paper›PMID 31768077›Full record

ArticleTetrahedron2019

Organoselenium-catalyzed enantioselective

Bradley B Gilbert, Stanley T-C Eey, Pavel Ryabchuk, Olivia Garry, Scott E Denmark

Abstract read
In one paragraph

Article in Tetrahedron, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.

0numbers the graph read from it
0cells of the map it votes in
12citing papers in PubMed
2.6field-weighted citation impact, top 10% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

12 citing papers in PubMed, 43 citations in OpenAlex.

  1. Article
  2. Enriching AlkeneOrganic letters · 2026
    Article
  3. Article
  4. Article
  5. Article
  6. Article
  7. Review
  8. Article
  9. The Electrochemical cis-Chlorination of Alkenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021
    Article
  10. Article
  11. Article
  12. Catalytic, EnantioselectiveJournal of the American Chemical Society · 2019
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors at 1 institution in 1 country.

Bradley B GilbertDepartment of Chemistry, University of Illinois, 600 S. Mathews Ave. Urbana, IL 61801, USA.
Stanley T-C EeyDepartment of Chemistry, University of Illinois, 600 S. Mathews Ave. Urbana, IL 61801, USA.
Pavel RyabchukDepartment of Chemistry, University of Illinois, 600 S. Mathews Ave. Urbana, IL 61801, USA.
Olivia GarryDepartment of Chemistry, University of Illinois, 600 S. Mathews Ave. Urbana, IL 61801, USA.
Scott E DenmarkDepartment of Chemistry, University of Illinois, 600 S. Mathews Ave. Urbana, IL 61801, USA.
University of Illinois Urbana-Champaign · US

Funding

Organosilicon-Based Cross-Coupling ReactionsR01GM063167 · NIGMS · UNIVERSITY OF ILLINOIS URBANA-CHAMPAIGN · PI DENMARK, SCOTT ERIC · 2002 to 2009
$2.5M
Asymmetric Lewis Base Catalysis in Main Group ChemistryR01GM085235 · NIGMS · UNIVERSITY OF ILLINOIS AT URBANA-CHAMPAIGN · PI DENMARK, SCOTT ERIC · 2010 to 2017
$2.4M
THE CYCLOADDITION CHEMISTRY OF NITROALKENESR01GM030938 · NIGMS · UNIVERSITY OF ILLINOIS URBANA-CHAMPAIGN · PI DENMARK, SCOTT ERIC · 1985 to 2007
$2.1M
CHEMISTRY OF CHIRAL PHOSPHORUS-STABILIZED CARBANIONSR01GM045532 · NIGMS · UNIVERSITY OF ILLINOIS URBANA-CHAMPAIGN · PI DENMARK, SCOTT ERIC · 1991 to 1994
–
NIGMS NIH HHS R01 GM030938NIGMS NIH HHS R01 GM045532NIGMS NIH HHS R01 GM063167NIGMS NIH HHS R01 GM085235
6 · The paper itself

Abstract

The enantioselective dichlorination of alkenes is a continuing challenge in organic synthesis owing to the limitations of selective and independent antarafacial delivery of both electrophilic chlorenium and nucleophilic chloride to an olefin. Development of a general method for the enantioselective dichlorination of isolated alkenes would allow access to a wide variety of polyhalogenated natural products. Accordingly, the enantioselective

Indexed as

Electrophilic seleniumEnantioselective dichlorinationRedox catalysis

Identifiers

PMID31768077
PMCPMC6876749
OpenAlexW2947540950

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.