ArticleNature chemistry2020
Capturing intrinsic site-dependent spectral signatures and lifetimes of isolated OH oscillators in extended water networks.
Article in Nature chemistry, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed, 42 citations in OpenAlex.
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- State-resolved infrared spectrum of the protonated water dimer: revisiting the characteristic proton transfer doublet peak.Chemical science · 2022Article
- Unraveling hydridic-to-protonic dihydrogen bond predominance in monohydrated dodecaborate clusters.Chemical science · 2022Article
- Towards complete assignment of the infrared spectrum of the protonated water cluster HNature communications · 2021Article
- Auf zur Wasserstoffentwicklung: Das Infrarot-Spektrum von hydratisiertem Aluminiumhydrid-Hydroxid HAlOHAngewandte Chemie (Weinheim an der Bergstrasse, Germany) · 2021Article
- Getting Ready for the Hydrogen Evolution Reaction: The Infrared Spectrum of Hydrated Aluminum Hydride-Hydroxide HAlOHAngewandte Chemie (International ed. in English) · 2021Article
- Asymmetric Solvation of the Zinc Dimer Cation Revealed by Infrared Multiple Photon Dissociation Spectroscopy of ZnInternational journal of molecular sciences · 2021Article
- Unexpected organic hydrate luminogens in the solid state.Nature communications · 2021Article
- How many water molecules are needed to solvate one?Chemical science · 2020Article
- Mapping the temperature-dependent and network site-specific onset of spectral diffusion at the surface of a water cluster cage.Proceedings of the National Academy of Sciences of the United States of America · 2020Article
- Structural evolution of water and hydroxyl groups during thermal, mechanical and chemical treatment of high purity natural quartz.RSC advances · 2020Article
- Structure and solvation of confined water and water-ethanol clusters within microporous Brønsted acids and their effects on ethanol dehydration catalysis.Chemical science · 2020Article
Corrections and comments
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Authors and funding
4 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The extremely broad infrared spectrum of water in the OH stretching region is a manifestation of how profoundly a water molecule is distorted when embedded in its extended hydrogen-bonding network. Many effects contribute to this breadth in solution at room temperature, which raises the question as to what the spectrum of a single OH oscillator would be in the absence of thermal fluctuations and coupling to nearby OH groups. We report the intrinsic spectral responses of isolated OH oscillators embedded in two cold (~20 K), hydrogen-bonded water cages adopted by the Cs
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