Evidence map›Paper›PMID 31763754›Full record

ArticleAngewandte Chemie (International ed. in English)2020

Tiara[5]arenes: Synthesis, Solid-State Conformational Studies, Host-Guest Properties, and Application as Nonporous Adaptive Crystals.

Weiwei Yang, Kushal Samanta, Xintong Wan, Tushar Ulhas Thikekar, Yang Chao, Shunshun Li, Ke Du, Jun Xu, Yan Gao, Han Zuilhof and 1 more

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 35 papers.

0numbers the graph read from it
0cells of the map it votes in
35citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

35 citing papers in PubMed.

  1. Article
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  5. Review
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  11. Review
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  13. Article
  14. Review
  15. Article
  16. A Water-Soluble Leggero Pillar[5]arene.Molecules (Basel, Switzerland) · 2022
    Article
  17. Adsorptive separation ofRSC advances · 2022
    Article
  18. Article
  19. Article
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Weiwei YangInstitute for Molecular Design and Synthesis, School of Pharmaceutical Science & Technology, Tianjin University, 92 Weijin Road, Nankai District, Tianjin, 300072, P. R. China.ORCID http://orcid.org/0000-0003-3062-6023
Kushal SamantaInstitute for Molecular Design and Synthesis, School of Pharmaceutical Science & Technology, Tianjin University, 92 Weijin Road, Nankai District, Tianjin, 300072, P. R. China.ORCID http://orcid.org/0000-0002-7414-4475
Xintong WanInstitute for Molecular Design and Synthesis, School of Pharmaceutical Science & Technology, Tianjin University, 92 Weijin Road, Nankai District, Tianjin, 300072, P. R. China.ORCID http://orcid.org/0000-0002-5792-0030
Tushar Ulhas ThikekarInstitute for Molecular Design and Synthesis, School of Pharmaceutical Science & Technology, Tianjin University, 92 Weijin Road, Nankai District, Tianjin, 300072, P. R. China.ORCID http://orcid.org/0000-0001-9037-5292
Yang ChaoInstitute for Molecular Design and Synthesis, School of Pharmaceutical Science & Technology, Tianjin University, 92 Weijin Road, Nankai District, Tianjin, 300072, P. R. China.ORCID http://orcid.org/0000-0002-1383-1693
Shunshun LiInstitute for Molecular Design and Synthesis, School of Pharmaceutical Science & Technology, Tianjin University, 92 Weijin Road, Nankai District, Tianjin, 300072, P. R. China.ORCID http://orcid.org/0000-0001-5322-2537
Ke DuInstitute for Molecular Design and Synthesis, School of Pharmaceutical Science & Technology, Tianjin University, 92 Weijin Road, Nankai District, Tianjin, 300072, P. R. China.ORCID http://orcid.org/0000-0002-1786-7327
Jun XuInstitute for Molecular Design and Synthesis, School of Pharmaceutical Science & Technology, Tianjin University, 92 Weijin Road, Nankai District, Tianjin, 300072, P. R. China.ORCID http://orcid.org/0000-0002-2562-2872
Yan GaoInstitute for Molecular Design and Synthesis, School of Pharmaceutical Science & Technology, Tianjin University, 92 Weijin Road, Nankai District, Tianjin, 300072, P. R. China.ORCID http://orcid.org/0000-0001-9406-0538
Han ZuilhofInstitute for Molecular Design and Synthesis, School of Pharmaceutical Science & Technology, Tianjin University, 92 Weijin Road, Nankai District, Tianjin, 300072, P. R. China.ORCID http://orcid.org/0000-0001-5773-8506
Andrew C-H SueInstitute for Molecular Design and Synthesis, School of Pharmaceutical Science & Technology, Tianjin University, 92 Weijin Road, Nankai District, Tianjin, 300072, P. R. China.ORCID http://orcid.org/0000-0001-9557-2658

Funding

National Basic Research Program of China (973 Program) 2015CB856500National Natural Science Foundation of China 21871208National Thousand Talents Young Investigator ProgramTianjin City 1000 Talents
6 · The paper itself

Abstract

Tiara[5]arenes (T[5]s), a new class of five-fold symmetric oligophenolic macrocycles that are not accessible from the addition of formaldehyde to phenol, were synthesized for the first time. These pillar[5]arene-derived structures display both unique conformational freedom, differing from that of pillararenes, with a rich blend of solid-state conformations and excellent host-guest interactions in solution. Finally we show how this novel macrocyclic scaffold can be functionalized in a variety of ways and used as functional crystalline materials to distinguish uniquely between benzene and cyclohexane.

Indexed as

five-fold symmetryhost-guest chemistrynonporous adaptive crystalspolymorphismtiara[5]arene

Identifiers

PMID31763754
PMCPMC7187373

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.