ArticleChemistryOpen2019
Remote Control of the Synthesis of a [2]Rotaxane and its Shuttling via Metal-Ion Translocation.
Article in ChemistryOpen, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed, 17 citations in OpenAlex.
- Cooperative Effects in Switchable Catalysis: Enhancing Double-Click Reaction Yield of Symmetrical Rotaxanes.Angewandte Chemie (International ed. in English) · 2021Article
- Remote Control of the Synthesis of a [2]Rotaxane and its Shuttling via Metal-Ion Translocation.ChemistryOpen · 2019Article
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Authors and funding
4 authors at 2 institutions in 1 country.
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Abstract
Remote control in an eight-component network commanded both the synthesis and shuttling of a [2]rotaxane via metal-ion translocation, the latter being easily monitored by distinct colorimetric and fluorimetric signals. Addition of zinc(II) ions to the red colored copper-ion relay station rapidly liberated copper(I) ions and afforded the corresponding zinc complex that was visualized by a bright sky blue fluorescence at 460 nm. In a mixture of all eight components of the network, the liberated copper(I) ions were translocated to a macrocycle that catalyzed formation of a rotaxane by a double-click reaction of acetylenic and diazide compounds. The shuttling frequency in the copper-loaded [2]rotaxane was determined to
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