ArticleChemSusChem2020
Effect of Water and Alkali-Ion Content on the Structure of Manganese(II) Hexacyanoferrate(II) by a Joint Operando X-ray Absorption Spectroscopy and Chemometric Approach.
Article in ChemSusChem, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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Who cites it
9 citing papers in PubMed.
- Functional binder engineering for Prussian blue analogue cathodes: mechanistic insights, cross-system inspiration, and design principles.Chemical science · 2026Review
- Highlighting Charge Redistribution Phenomenon in Mn-Based Prussian Blue Analogues for Enhancing Redox Stability.ChemSusChem · 2025Article
- Cation-self-shielding strategy promises high-voltage all-Prussian-blue-based aqueous K-ion batteries.Nature communications · 2025Article
- Operando Synchrotron X-Ray Absorption Spectroscopy: A Key Tool for Cathode Material Studies in Next-Generation Batteries.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Review
- A Self-Constructed MgAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- In Situ Growth of Sodium Manganese Hexacyanoferrate on Carbon Nanotubes for High-Performance Sodium-Ion Batteries.Molecules (Basel, Switzerland) · 2024Article
- Defect-free potassium manganese hexacyanoferrate cathode material for high-performance potassium-ion batteries.Nature communications · 2021Article
- Trends in artificial intelligence, machine learning, and chemometrics applied to chemical data.Analytical science advances · 2021Review
- Article
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Authors and funding
5 authors.
Funding
Abstract
Manganese hexacyanoferrate (MnHCF) is made of earth-abundant elements by a safe and easy synthesis. The material features a higher specific capacity at a higher potential than other Prussian blue analogs. However, the effect of hydration is critical to determine the electrochemical performance as both the electrochemical behavior and the reaction dynamics are affected by interstitial/structural water and adsorbed water. In this study, the electrochemical activity of MnHCF is investigated by varying the interstitial ion content through a joint operando X-ray absorption spectroscopy and chemometric approach, with the intent to assess the structural and electronic modifications that occur during Na release and Li insertion, as well as the overall dynamic evolution of the system. In MnHCF, both the Fe and Mn centers are electrochemically active and undergo reversible oxidation during the interstitial ion extraction (Fe
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Registered trials
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