ArticleNature chemistry2019
Iron(II) coordination complexes with panchromatic absorption and nanosecond charge-transfer excited state lifetimes.
Article in Nature chemistry, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 60 papers.
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Who cites it
60 citing papers in PubMed.
- Synthetic Mechanism of a Fe(II)Inorganic chemistry · 2026Article
- Kinetics vs Thermodynamics: Engineering Photoredox Reactivity from an Upper Excited State of FeJournal of the American Chemical Society · 2026Article
- High-efficiency electro-Fenton mineralization of triclosan using a novel octahedral iron(iii) complex: structure, mechanism, and performance.RSC advances · 2026Article
- Base Metal Photocatalysts: A Bright Future in Photoredox Catalysis?Organometallics · 2026Article
- Photooxidative Copper(II) Catalysis for Promoting anti-Markovnikov Hydration of Alkenes.Nature communications · 2026Article
- Substitution Kinetics, DNA/BSA Interactions, Cytotoxicity Evaluation and Computational Analysis of [Bioinorganic chemistry and applications · 2026Article
- Homomolecular Photon Upconversion in a Perylene-Decorated Iron(III) Complex.Journal of the American Chemical Society · 2025Article
- Beyond Common Energy Transfer: Intramolecular Electron Transfer Cascade Controls Triplet Population of a Long-Lived Iron-Anthracene Molecular Dyad.ACS central science · 2025Article
- Unraveling the photoredox chemistry of a molecular ruby.Chemical science · 2025Article
- Understanding Anomalous Cage-Escape Dynamics in Photoredox Processes Driven by a Fe(III) N-Heterocyclic Carbene Complex.Journal of the American Chemical Society · 2025Article
- Structural Control of Metal-Centered Excited States in Cobalt(III) Complexes via Bite Angle and π-π Interactions.Journal of the American Chemical Society · 2025Article
- A Heterodox Approach for Designing Iron Photosensitizers: Pentacyanoferrate(II) Complexes with Monodentate Bipyridinium/Pyrazinium-Based Acceptor Ligands.Inorganic chemistry · 2025Article
- Molecular Design Principles for Photoactive Transition Metal Complexes: A Guide for "Photo-Motivated" Chemists.Journal of the American Chemical Society · 2025Review
- Making Mo(0) a Competitive Alternative to Ir(III) in Phosphors and Photocatalysts.Journal of the American Chemical Society · 2025Article
- Site-Selective Ligand Functionalization Reverses Hypsochromic Luminescence Shifts in Platinum(II) Complexes of Benzannulated NCN-Coordinating Ligands.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Establishing the origin of Marcus-inverted-region behaviour in the excited-state dynamics of cobalt(III) polypyridyl complexes.Nature chemistry · 2024Article
- Enter MnJournal of the American Chemical Society · 2024Article
- Exploring the Photophysics and Photocatalytic Activity of Heteroleptic Rh(III) Transition-Metal Complexes Using High-Throughput Experimentation.Inorganic chemistry · 2024Article
- Iron(III) Carbene Complexes with Tunable Excited State Energies for Photoredox and Upconversion.Journal of the American Chemical Society · 2024Article
- Femtosecond Infrared Spectroscopy Resolving the Multiplicity of High-Spin Crossover States in Transition Metal Iron Complexes.Journal of the American Chemical Society · 2024Article
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Replacing current benchmark rare-element photosensitizers with ones based on abundant and low-cost metals such as iron would help facilitate the large-scale implementation of solar energy conversion. To do so, the ability to extend the lifetimes of photogenerated excited states of iron complexes is critical. Here, we present a sensitizer design in which iron(II) centres are supported by frameworks containing benzannulated phenanthridine and quinoline heterocycles paired with amido donors. These complexes exhibit panchromatic absorption and nanosecond charge-transfer excited state lifetimes, enabled by the combination of vacant, energetically accessible heterocycle-based acceptor orbitals and occupied molecular orbitals destabilized by strong mixing between amido nitrogen atoms and iron. This finding shows how ligand design can extend metal-to-ligand charge-transfer-type excited state lifetimes of iron(II) complexes into the nanosecond regime and expand the range of potential applications for iron-based photosensitizers.
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31740761What OpenQuestion holds
Registered trials
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