ArticleAngewandte Chemie (International ed. in English)2020
Stereodivergent Anion Binding Catalysis with Molecular Motors.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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Who cites it
18 citing papers in PubMed.
- A Molecular Machine Directs the Synthesis of a Rotaxane.Angewandte Chemie (International ed. in English) · 2026Article
- General Synthetic Methodologies for Building Blocks to Construct Molecular Motors.The Journal of organic chemistry · 2025Review
- Enlightening dynamic functions in molecular systems by intrinsically chiral light-driven molecular motors.Chemical Society reviews · 2023Review
- Accounts of applied molecular rotors and rotary motors: recent advances.Nanoscale advances · 2023Review
- Synthesis of functionalised isochromans: epoxides as aldehyde surrogates in hexafluoroisopropanol.Chemical science · 2023Article
- Adaptive 2D and Pseudo-2D Systems: Molecular, Polymeric, and Colloidal Building Blocks for Tailored Complexity.Nanomaterials (Basel, Switzerland) · 2023Review
- Mechanism of a Dually Catalyzed Enantioselective Oxa-Pictet-Spengler Reaction and the Development of a Stereodivergent Variant.ACS catalysis · 2023Article
- Chemically Driven Rotatory Molecular Machines.Angewandte Chemie (International ed. in English) · 2022Review
- Enantiodivergent epoxidation of alkenes with a photoswitchable phosphate manganese-salen complex.Nature synthesis · 2022Article
- Controlling rotary motion of molecular motors based on oxindole.Organic chemistry frontiers : an international journal of organic chemistry · 2022Article
- Dynamic Control of a Multistate Chiral Supramolecular Polymer in Water.Journal of the American Chemical Society · 2022Article
- Designing light-driven rotary molecular motors.Chemical science · 2021Review
- A Switchable Catalyst Duo for Acyl Transfer Proximity Catalysis and Regulation of Substrate Selectivity.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Visible-Light-Driven Rotation of Molecular Motors in Discrete Supramolecular Metallacycles.Journal of the American Chemical Society · 2021Article
- Halides as versatile anions in asymmetric anion-binding organocatalysis.Beilstein journal of organic chemistry · 2021Review
- Insight into the Folding and Cooperative Multi-Recognition Mechanism in Supramolecular Anion-Binding Catalysis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Stereodivergent Anion Binding Catalysis with Molecular Motors.Angewandte Chemie (International ed. in English) · 2020Article
- Azo-dimethylaminopyridine-functionalized Ni(II)-porphyrin as a photoswitchable nucleophilic catalyst.Beilstein journal of organic chemistry · 2020Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
A photoresponsive chiral catalyst based on an oligotriazole-functionalized unidirectional molecular motor has been developed for stereodivergent anion binding catalysis. The motor function controls the helical chirality of supramolecular assemblies with chloride anions, which by means of chirality transfer enables the enantioselective addition of a silyl ketene acetal nucleophile to oxocarbenium cations. Reversal of stereoselectivity (up to 142 % Δee) was achieved through rotation of the motor core induced by photochemical and thermal isomerization steps.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.