ArticleAngewandte Chemie (International ed. in English)2020
Oxodealkenylative Cleavage of Alkene C(sp
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed, 35 citations in OpenAlex.
- Chemical Recycling of Waste Wind-Turbine Blades Through Polymer Deconstruction and Upcycling.ChemSusChem · 2026Review
- Iron-Catalyzed Dealkenylative Borylation of Alkenes via Ozonolysis.Journal of the American Chemical Society · 2026Article
- Terpenes as Naturally Occurring Stereochemical Templates: Conformationally Driven Discovery of Reactivity.Organic letters · 2025Article
- Article
- Synthesis through C(spAccounts of chemical research · 2025Article
- Hydrodealkenylative C(spJournal of the American Chemical Society · 2025Article
- Alkene Diversification through a Molecular Recasting Strategy Enabled byResearch (Washington, D.C.) · 2025Article
- Halodealkenylation: Ozonolysis and Catalytic FeOrganic letters · 2024Article
- Oxoammonium-Catalyzed Oxidation ofJournal of the American Chemical Society · 2024Article
- Hydrodealkenylative Cleavage of C(spOrganic syntheses; an annual publication of satisfactory methods for the preparation of organic chemicals · 2024Article
- Dealkenylative Functionalizations: Conversion of Alkene C(spSynthesis · 2024Article
- When all C-C breaks LO-Ose.Trends in chemistry · 2023Article
- Dealkenylative Alkynylation Using Catalytic FeJournal of the American Chemical Society · 2022Article
- Site-Specific and Degree-Controlled Alkyl Deuteration via Cu-Catalyzed Redox-Neutral Deacylation.Journal of the American Chemical Society · 2022Article
- Site-selective amination and/or nitrilationChemical science · 2022Article
- C-H Insertion via Ruthenium CatalyzedJournal of the American Chemical Society · 2022Article
- Dealkenylative Alkenylation: Formal σ-Bond Metathesis of Olefins.Angewandte Chemie (International ed. in English) · 2020Article
Corrections and comments
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Authors and funding
9 authors at 1 institution in 1 country.
Funding
Abstract
Reported herein is a one-pot protocol for the oxodealkenylative introduction of carbonyl functionalities into terpenes and terpene-derived compounds. This transformation proceeds by Criegee ozonolysis of an alkene, reductive cleavage of the resulting α-alkoxy hydroperoxide, trapping of the generated alkyl radical with 2,2,6,6-tetramethylpiperidin-1-yl (TEMPO), and subsequent oxidative fragmentation with MMPP. Using readily available starting materials from chiral pool, a variety of carbonyl-containing products have been accessed rapidly in good yields.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.