Evidence map›Paper›PMID 31671244›Full record

ArticleAngewandte Chemie (International ed. in English)2019

Snapshots of Dynamic Adaptation: Two-Dimensional Molecular Architectonics with Linear Bis-Hydroxamic Acid Modules.

Chao Jing, Bodong Zhang, Sabine Synkule, Maryam Ebrahimi, Alexander Riss, Willi Auwärter, Li Jiang, Guillaume Médard, Joachim Reichert, Johannes V Barth and 1 more

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Rotation in an Enantiospecific Self-Assembled Array of Molecular Raffle Wheels.Angewandte Chemie (International ed. in English) · 2021
    Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Chao JingPhysics Department E20, Technical University of Munich, James Franck Straße 1, 85748, Garching, Germany.ORCID http://orcid.org/0000-0003-0339-9742
Bodong ZhangPhysics Department E20, Technical University of Munich, James Franck Straße 1, 85748, Garching, Germany.
Sabine SynkulePhysics Department E20, Technical University of Munich, James Franck Straße 1, 85748, Garching, Germany.
Maryam EbrahimiPhysics Department E20, Technical University of Munich, James Franck Straße 1, 85748, Garching, Germany.ORCID http://orcid.org/0000-0003-1421-2971
Alexander RissPhysics Department E20, Technical University of Munich, James Franck Straße 1, 85748, Garching, Germany.ORCID http://orcid.org/0000-0002-3212-7925
Willi AuwärterPhysics Department E20, Technical University of Munich, James Franck Straße 1, 85748, Garching, Germany.ORCID http://orcid.org/0000-0001-9452-4662
Li JiangPhysics Department E20, Technical University of Munich, James Franck Straße 1, 85748, Garching, Germany.
Guillaume MédardChair of Proteomics and Bioanalytics, Technical University of Munich, Emil Erlenmeyer Forum 5, 85354, Freising, Germany.ORCID http://orcid.org/0000-0002-4782-4029
Joachim ReichertPhysics Department E20, Technical University of Munich, James Franck Straße 1, 85748, Garching, Germany.
Johannes V BarthPhysics Department E20, Technical University of Munich, James Franck Straße 1, 85748, Garching, Germany.ORCID http://orcid.org/0000-0002-6270-2150
Anthoula C PapageorgiouPhysics Department E20, Technical University of Munich, James Franck Straße 1, 85748, Garching, Germany.ORCID http://orcid.org/0000-0003-1054-0097

Funding

China Scholarship CouncilDeutsche Forschungsgemeinschaft 267156538Deutsche Forschungsgemeinschaft EXC 158H2020 European Research Council 615233Horizon 2020 664878Max Planck Research School of Advanced Photon SciencePostdoctoral Research Foundation of China
6 · The paper itself

Abstract

Linear modules equipped with two terminal hydroxamic acid groups act as the building block of diverse two-dimensional supramolecular motifs and patterns with room-temperature stability on the close-packed single-crystal surfaces of silver and gold, revealing a complex self-assembly scenario. By combining multiple investigation techniques (scanning tunneling microscopy, atomic force microscopy, X-ray photoelectron spectroscopy, and density functional theory calculations), we analyze the characteristics of the ordered assemblies which range from close-packed structures to polyporous networks featuring an exceptionally extended primitive unit cell with a side length exceeding 7 nm. The polyporous network shows potential for hosting and promoting the formation of chiral supramolecules, whereas a transition from 1D chiral randomness to an ordered racemate is discovered in a different porous phase. We correlate the observed structural changes to the adaptivity of the building block and surface-induced changes in the chemical state of the hydroxamic acid functional group.

Indexed as

atomic force microscopyhost-guest systemshydroxamic acidscanning tunneling microscopytwo-dimensional nanostructures

Identifiers

PMID31671244
PMCPMC6973039

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.