ArticleSynthesis2019
Transition-Metal-Catalyzed Alkyl Heck-Type Reactions.
Article in Synthesis, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 31 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
31 citing papers in PubMed.
- Photoinduced Palladium-Catalyzed Site-Selective Meta-Alkylation of Pyridines.Angewandte Chemie (International ed. in English) · 2026Article
- Redox-neutral ketone-olefin coupling enabled by mild ketone-to-ketyl-type radical conversion.Nature chemistry · 2026Article
- Cobaloxime Catalysis: A General Platform for Mizoroki-Heck-Type Reactions and Catalytic Dehydrohalogenations of Unactivated Alkyl Chlorides.Journal of the American Chemical Society · 2026Article
- Recent Advances in Homogeneous Catalysis with Platinum Group Pincer Complexes: Hydrogen-Mediated Transformations and Cross-Coupling Reactions.Chemical record (New York, N.Y.) · 2026Review
- Excited-State Palladium-Catalyzed Radical Allylic Alkylation: Rapid Access to C2-Allyl Carbohydrates.ACS catalysis · 2025Article
- Bismuth-photocatalysed Heck-type coupling with alkyl and aryl electrophiles.Nature catalysis · 2025Article
- α-Halocarbonyls as a Valuable Functionalized Tertiary Alkyl Source.ChemistryOpen · 2024Review
- Review
- Visible-Light-Driven Regioselective Decarboxylative Acylation ofACS omega · 2024Article
- One-Pot Formal Carboradiofluorination of Alkenes: A Toolkit for Positron Emission Tomography Imaging Probe Development.Journal of the American Chemical Society · 2023Article
- Enhanced Excited-State Hydricity of Pd-H Allows for Unusual Head-to-Tail Hydroalkenylation of Alkenes.Journal of the American Chemical Society · 2023Article
- Excited-State Copper-Catalyzed [4 + 1] Annulation Reaction Enables Modular Synthesis of α,β-Unsaturated-γ-Lactams.Journal of the American Chemical Society · 2022Article
- Palladium Hydride-Enabled Hydroalkenylation of Strained Molecules.Journal of the American Chemical Society · 2022Article
- Divergent regioselective Heck-type reaction of unactivated alkenes and N-fluoro-sulfonamides.Nature communications · 2022Article
- Pd(II)-Catalyzed Synthesis of Bicyclo[3.2.1] LactonesJournal of the American Chemical Society · 2022Article
- Accessing IllusiveOrganic letters · 2022Article
- C2-ketonylation of carbohydratesChemical science · 2022Article
- A Fluorescent Linear Conjugated Polymer Constructed from Pillararene and Anthracene.Molecules (Basel, Switzerland) · 2022Article
- Excited-State Palladium-Catalyzed Radical Migratory Mizoroki-Heck Reaction Enables C2-Alkenylation of Carbohydrates.Journal of the American Chemical Society · 2022Article
- Asymmetric Photocatalysis Enabled by Chiral Organocatalysts.ChemCatChem · 2022Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
The Heck reaction is one of the most reliable and useful strategies for the construction of C-C bonds in organic synthesis. However, in contrast to the well-established aryl Heck reaction, the analogous reaction employing alkyl electrophiles is much less developed. Significant progress in this area was recently achieved by merging radical-mediated and transition-metal-catalyzed approaches. This review summarizes the advances in alkyl Heck-type reactions from its discovery early in the 1970s up until the end of 2018.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.