ArticleChemistry (Weinheim an der Bergstrasse, Germany)2019
Iron-Electrocatalyzed C-H Arylations: Mechanistic Insights into Oxidation-Induced Reductive Elimination for Ferraelectrocatalysis.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
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Who cites it
22 citing papers in PubMed, 67 citations in OpenAlex.
- Coordination-Induced Spin Modulation: Overcoming Spin Blocking in C-H Methylation with High-Spin Ferrous Complexes.ACS catalysis · 2026Article
- Fe-electrocatalytic deoxygenative Giese reaction.Nature communications · 2025Article
- Iron(III)-Mediated C-H Alkylation: One-Electron Differentiation Increases Activity and Chemoselectivity.Journal of the American Chemical Society · 2025Article
- Unlocking Catalysis Using Oxidatively Induced Reductive Elimination.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Review
- Redox-Neutral, Iron-Mediated Directed C-H Activation: General Principles and Mechanistic Insights.Journal of the American Chemical Society · 2024Article
- Palladium-Catalyzed Electrooxidative Double C-H Arylation.Journal of the American Chemical Society · 2024Article
- Chelation-Assisted Iron-Catalyzed C-H Activations: Scope and Mechanism.Accounts of chemical research · 2024Article
- Ruthenaelectro-catalyzed C-H acyloxylation for late-stage tyrosine and oligopeptide diversification.Chemical science · 2022Article
- Traditional and sustainable approaches for the construction of C-C bonds by harnessing C-H arylation.Nature communications · 2022Review
- Electrocatalysis as an enabling technology for organic synthesis.Chemical Society reviews · 2021Article
- Mediator-Enabled Electrocatalysis with Ligandless Copper for Anaerobic Chan-Lam Coupling Reactions.Journal of the American Chemical Society · 2021Article
- Organic Electrochemistry: Molecular Syntheses with Potential.ACS central science · 2021Review
- Electroreductive Nickel-Catalyzed Thiolation: Efficient Cross-Electrophile Coupling for C-S Formation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Facilitating Ir-Catalyzed C-H Alkynylation with Electrochemistry: Anodic Oxidation-Induced Reductive Elimination.ACS catalysis · 2020Article
- Evolution of High-Valent Nickela-Electrocatalyzed C-H Activation: From Cross(-Electrophile)-Couplings to Electrooxidative C-H Transformations.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Review
- Nickela-electrocatalyzed Mild C-H Alkylations at Room Temperature.Angewandte Chemie (International ed. in English) · 2020Article
- Renewable resources for sustainable metallaelectro-catalysed C-H activation.Chemical science · 2020Review
- Electroreductive Cobalt-Catalyzed Carboxylation: Cross-Electrophile Electrocoupling with Atmospheric COAngewandte Chemie (International ed. in English) · 2020Article
- Azaruthena(II)-bicyclo[3.2.0]heptadiene: Key Intermediate for Ruthenaelectro(II/III/I)-catalyzed Alkyne Annulations.Angewandte Chemie (International ed. in English) · 2020Article
- Iron-Catalyzed C-H Functionalizations under Triazole-Assistance.Molecules (Basel, Switzerland) · 2020Review
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Authors and funding
5 authors at 1 institution in 1 country.
Funding
Abstract
Despite major advances, organometallic C-H transformations are dominated by precious 5d and 4d transition metals, such as iridium, palladium and rhodium. In contrast, the unique potential of less toxic Earth-abundant 3d metals has been underexplored. While iron is the most naturally abundant transition metal, its use in oxidative, organometallic C-H activation has faced major limitations due to the need for superstoichiometric amounts of corrosive, cost-intensive DCIB as the sacrificial oxidant. To fully address these restrictions, we describe herein the unprecedented merger of electrosynthesis with iron-catalyzed C-H activation through oxidation-induced reductive elimination. Thus, ferra- and manganaelectro-catalyzed C-H arylations were accomplished at mild reaction temperatures with ample scope by the action of sustainable iron catalysts, employing electricity as a benign oxidant.
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