ArticleOrganic & biomolecular chemistry2019
Tailoring chemoenzymatic oxidation via in situ peracids.
Article in Organic & biomolecular chemistry, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Glutaraldehyde-crosslinked Rhizopus oryzae whole cells show improved catalytic performance in alkene epoxidation.Microbial cell factories · 2023Article
- Impact of Different Epoxidation Approaches of Tall Oil Fatty Acids on Rigid Polyurethane Foam Thermal Insulation.Materials (Basel, Switzerland) · 2021Article
- Sequence-Based Prediction of Promiscuous Acyltransferase Activity in Hydrolases.Angewandte Chemie (International ed. in English) · 2020Article
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Authors and funding
5 authors.
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Abstract
Epoxidation chemistry often suffers from the challenging handling of peracids and thus requires in situ preparation. Here, we describe a two-phase enzymatic system that allows the effective generation of peracids and directly translate their activity to the epoxidation of olefins. We demonstrate the approach by application to lipid and olefin epoxidation as well as sulfide oxidation. These methods offer useful applications to synthetic modifications and scalable green processes.
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