ArticleNature communications2019
Single- and multi-component chiral supraparticles as modular enantioselective catalysts.
Article in Nature communications, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 29 papers, 1 of them a synthesis that pooled it.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
29 citing papers in PubMed, 1 synthesis or guideline pooled it, 142 citations in OpenAlex.
- Chiral nanoenzymes: synthesis and applications.Mikrochimica acta · 2024Pooled it
- Advances and Prospects of Chiral Plasmonic Nanomaterials in Emerging Applications.Nanomaterials (Basel, Switzerland) · 2026Review
- General Synthesis of Chiral Mesostructured Carbonates Using Chiral Vicinal Polyhydroxy Molecules.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Spin-controlled enantioselective near-infrared photocatalysis with chiral MgO/CoNature communications · 2026Article
- Chirality Engineering and Properties in Two-Dimensional Layered Materials.Small (Weinheim an der Bergstrasse, Germany) · 2026Review
- Chiral Recognition Mechanism of 2,13-Bis(hydroxymethyl)-[7]thiaheterohelicene on Ag(111) Investigated by STM and MD Simulation.International journal of molecular sciences · 2025Article
- Chiral Imprinting on Inorganic Nanoparticles for Enantioselective Surface Recognition.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Spatial Control of Chiral Self-Assembly and Lithographic Applications in Liquid Crystal Polymer Network.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Chiral polypeptide hydrogels regulating local immune microenvironment and anti-tumor immune response.Nature communications · 2025Article
- Controlled Nanopore Sizes in Supraparticle Supports for Enhanced Propane Dehydrogenation with GaPt SCALMS Catalysts.ACS applied nano materials · 2024Article
- Biomimetic Chiral Nanomaterials with Selective Catalysis Activity.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Review
- Expanding the Horizons of Machine Learning in Nanomaterials to Chiral Nanostructures.Advanced materials (Deerfield Beach, Fla.) · 2024Review
- Emerging trends in chiral inorganic nanomaterials for enantioselective catalysis.Nature communications · 2024Review
- Tapered chiral nanoparticles as broad-spectrum thermally stable antivirals for SARS-CoV-2 variants.Proceedings of the National Academy of Sciences of the United States of America · 2024Article
- Multicomponent chiral plasmonic hybrid nanomaterials: recent advances in synthesis and applications.Nanoscale advances · 2024Review
- Nature-Inspired Chiral Structures: Fabrication Methods and Multifaceted Applications.Biomimetics (Basel, Switzerland) · 2023Review
- Chiral Nanoparticle Chains on Inorganic Nanotube Templates.Nano letters · 2023Article
- The potential of converting carbon dioxide to food compoundsNanoscale advances · 2023Review
- Versatile fabrication of metal sulfide supraparticles by anNanoscale advances · 2023Article
- Biomimetic Self-Assembled Chiral Inorganic Nanomaterials: A New Strategy for Solving Medical Problems.Biomimetics (Basel, Switzerland) · 2022Review
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
7 authors at 3 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Nanoscale biological assemblies exemplified by exosomes, endosomes and capsids, play crucial roles in all living systems. Supraparticles (SP) from inorganic nanoparticles (NPs) replicate structural characteristics of these bioassemblies, but it is unknown whether they can mimic their biochemical functions. Here, we show that chiral ZnS NPs self-assemble into 70-100 nm SPs that display sub-nanoscale porosity associated with interstitial spaces between constituent NPs. Similarly to photosynthetic bacterial organelles, these SPs can serve as photocatalysts, enantioselectively converting L- or D-tyrosine (Tyr) into dityrosine (diTyr). Experimental data and molecular dynamic simulations indicate that the chiral bias of the photocatalytic reaction is associated with the chiral environment of interstitial spaces and preferential partitioning of enantiomers into SPs, which can be further enhanced by co-assembling ZnS with Au NPs. Besides replicating a specific function of biological nanoassemblies, these findings establish a path to enantioselective oxidative coupling of phenols for biomedical and other needs.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.