ArticlePolymers2019
Organic Zinc Salts as Pro-Ecological Activators for Sulfur Vulcanization of Styrene-Butadiene Rubber.
Article in Polymers, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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17 citing papers in PubMed, 45 citations in OpenAlex.
- The Effect of the Addition of Sage (Materials (Basel, Switzerland) · 2025Article
- Article
- Elastomeric Biocomposites of Natural Rubber Containing Biosynthesized Zinc Oxide.International journal of molecular sciences · 2025Article
- Alfalfa/Lucerne (Polymers · 2024Article
- Article
- Preparation of Zinc Oxide with Core-Shell Structure and Its Application in Rubber Products.Polymers · 2023Article
- The Influence of Freeze-Dried Alcohol-Water Extracts from Common Yarrow (International journal of molecular sciences · 2022Article
- Structure and Stability Characterization of Natural Lake Pigments Made from Plant Extracts and Their Potential Application in Polymer Composites for Packaging Materials.Materials (Basel, Switzerland) · 2022Article
- Antioxidant and Anti-Aging Activity of Freeze-Dried Alcohol-Water Extracts from Common Nettle (Polymers · 2022Article
- Comparison of Aging Resistance and Antimicrobial Properties of Ethylene-Norbornene Copolymer and Poly(Lactic Acid) Impregnated with Phytochemicals Embodied in Thyme (International journal of molecular sciences · 2021Article
- Investigation into the Effect of Spinel Pigments on the Photostability and Combustion Properties of Ethylene-Norbornene Copolymer.Materials (Basel, Switzerland) · 2021Article
- Potential Application of Peppermint (International journal of molecular sciences · 2021Article
- Zinc Complexes with 1,3-Diketones as Activators for Sulfur Vulcanization of Styrene-Butadiene Elastomer Filled with Carbon Black.Materials (Basel, Switzerland) · 2021Article
- Natural Rubber Biocomposites Filled with Phyto-Ashes Rich in Biogenic Silica Obtained from Wheat Straw and Field Horsetail.Polymers · 2021Article
- Common Nettle (Materials (Basel, Switzerland) · 2021Article
- Horsetail (Materials (Basel, Switzerland) · 2020Article
- Thermoplastic Elastomeric Composites Filled with Lignocellulose Bioadditives, Part 2: Flammability, Thermo-Oxidative Aging Resistance, Mechanical and Barrier Properties.Materials (Basel, Switzerland) · 2020Article
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3 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Organic zinc salts and complexes were applied as activators for sulfur vulcanization of styrene-butadiene elastomer (SBR) in order to reduce the content of zinc ions in rubber compounds as compared with conventionally used zinc oxide. In this article, the effects of different organic zinc activators on the curing characteristics, crosslink densities, and mechanical properties of SBR as well as the aging resistance and thermal behavior of vulcanizates are discussed. Organic zinc salts seem to be good substitutes for zinc oxide as activators for sulfur vulcanization of SBR rubber, without detrimental effects to the vulcanization time and temperature. Moreover, vulcanizates containing organic zinc salts exhibit higher tensile strength and better damping properties than vulcanizate crosslinked with zinc oxide. The application of organic zinc activators allows the amount of zinc ions in SBR compounds to be reduced by 70-90 wt % compared to vulcanizate with zinc oxide. This is very important for ecological reasons, since zinc oxide is classified as being toxic to aquatic species.
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