ArticleNature communications2019
Hydrogen bonding structure of confined water templated by a metal-organic framework with open metal sites.
Article in Nature communications, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 35 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
35 citing papers in PubMed, 157 citations in OpenAlex.
- Interfacial Water State Engineering for Photocatalytic Hydrogen Evolution: From Immersed to Nonimmersed Systems.ChemSusChem · 2026Review
- Hydration Topology Manipulates COJACS Au · 2026Article
- Unraveling Water Sorption in Single-Crystal MOFs: Insights from Spectroscopy and Modeling on the Role of Structure, Composition, and Guest Molecules.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Water-generated dangling linkers in a metal-organic framework.Nature communications · 2026Article
- Optimizing Mixtures of Metal-Organic Frameworks for Robust and Bespoke Passive Atmospheric Water Harvesting.ACS engineering Au · 2025Article
- Decoding the Water Harvesting Mechanism of MIL-100(Fe) Across Short- and Long-Range Length Scales.Journal of the American Chemical Society · 2025Article
- Water Adsorption in Metal-Organic Frameworks: Characteristics, Mechanisms, and Structure-Property Relationships.Journal of the American Chemical Society · 2025Article
- High-capacity water sorbent cycles without hysteresis under dry conditions.Nature communications · 2025Article
- Recent Advances in Transition Metal-Based Metal-Organic Frameworks for Hydrogen Production.Small science · 2025Review
- Suppressing Jahn-Teller distortion of MnONature communications · 2025Article
- Water motifs in zirconium metal-organic frameworks induced by nanoconfinement and hydrophilic adsorption sites.Nature communications · 2024Article
- Dual Ionic Pathways in Semi-Solid Electrolyte based on Binary Metal-Organic Frameworks Enable Stable Operation of Li-Metal Batteries at Extremely High Temperatures.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Zeolite-promoted platinum catalyst for efficient reduction of nitrogen oxides with hydrogen.Nature communications · 2024Article
- Selective detection of food contaminants using engineered gallium-organic frameworks with MD and metadynamics simulations.Scientific reports · 2024Article
- Monitoring water harvesting in metal-organic frameworks, one water molecule at a time.Chemical science · 2024Article
- Selective Adsorption of Oxygen from Humid Air in a Metal-Organic Framework with Trigonal Pyramidal Copper(I) Sites.Journal of the American Chemical Society · 2024Article
- Hydrogen-Bonded Structures of Water Molecules in Hydroxy-Functionalized Nanochannels of Columnar Liquid Crystalline Nanostructured Membranes Studied by Soft X-ray Emission Spectroscopy.The journal of physical chemistry letters · 2024Article
- Water inside the Selectivity Filter of a KJournal of the American Chemical Society · 2024Article
- Water Harvesting at the Single-Crystal Level.Journal of the American Chemical Society · 2023Article
- Competitive and Cooperative COACS applied materials & interfaces · 2023Article
Corrections and comments
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Authors and funding
4 authors at 3 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Water in confinement exhibits properties significantly different from bulk water due to frustration in the hydrogen-bond network induced by interactions with the substrate. Here, we combine infrared spectroscopy and many-body molecular dynamics simulations to probe the structure and dynamics of confined water as a function of relative humidity within a metal-organic framework containing cylindrical pores lined with ordered cobalt open coordination sites. Building upon the agreement between experimental and theoretical spectra, we demonstrate that water at low relative humidity binds initially to open metal sites and subsequently forms disconnected one-dimensional chains of hydrogen-bonded water molecules bridging between cobalt atoms. With increasing relative humidity, these water chains nucleate pore filling, and water molecules occupy the entire pore interior before the relative humidity reaches 30%. Systematic analysis of rotational and translational dynamics indicates heterogeneity in this pore-confined water, with water molecules displaying variable mobility as a function of distance from the interface.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.