ArticleJournal of the American Chemical Society2019
Self-Healing Heterometallic Supramolecular Polymers Constructed by Hierarchical Assembly of Triply Orthogonal Interactions with Tunable Photophysical Properties.
Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
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Who cites it
19 citing papers in PubMed.
- Self-Healing Pd(II) Cage Metallogels for Iodine Capture in Water and Heterogeneous Photocatalysis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Photo- and thermo-responsive complementary metal coordination for the construction of supramolecular polymers.Chemical science · 2026Article
- Fluorescent Polymers via Coordination ofPolymers · 2024Article
- Nano/Micro-Structural Supramolecular Biopolymers: Innovative Networks with the Boundless Potential in Sustainable Agriculture.Nano-micro letters · 2024Review
- Exposing Mechanisms for Defect Clearance in Supramolecular Self-Assembly: Palladium-Pyridine Coordination Revisited.Inorganic chemistry · 2023Article
- Recent Advances in Stimuli-Responsive Metallogels.Molecules (Basel, Switzerland) · 2023Review
- AIEgen-Enabled Multicolor Visualization for the Formation of Supramolecular Polymer Networks.Molecules (Basel, Switzerland) · 2022Article
- Entropy directs the self-assembly of supramolecular palladium coordination macrocycles and cages.Chemical science · 2022Article
- Phenylthiol-BODIPY-based supramolecular metallacycles for synergistic tumor chemo-photodynamic therapy.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
- Non-Covalent Interaction on the Self-Healing of Mechanical Properties in Supramolecular Polymers.International journal of molecular sciences · 2022Review
- Visualizing molecular weights differences in supramolecular polymers.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
- A Two-Dimensional Metallacycle Cross-Linked Switchable Polymer for Fast and Highly Efficient Phosphorylated Peptide Enrichment.Journal of the American Chemical Society · 2021Article
- Stepwise introduction of three different transition metals in metallo-supramolecular polymer for quad-color electrochromism.Communications chemistry · 2021Article
- Polymeric Systems Containing Supramolecular Coordination Complexes for Drug Delivery.Polymers · 2021Review
- Hierarchical self-assembly of discrete bis-[2]pseudorotaxane metallacycle with bis-pillar[5]areneRSC advances · 2020Article
- Synthesis of an Alternated Heterobimetallic Supramolecular Polymer Based on Ru(II) and Fe(II).Molecules (Basel, Switzerland) · 2020Article
- An antibacterial and biocompatible multilayer biomedical coating capable of healing damages.RSC advances · 2020Article
- Recent developments in the construction and applications of platinum-based metallacycles and metallacages via coordination.Chemical Society reviews · 2020Article
- Fluorescent Supramolecular Polymers Formed by Crown Ether-Based Host-Guest Interaction.Frontiers in chemistry · 2020Review
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11 authors.
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Abstract
Here, we present a method for the building of new bicyclic heterometallic cross-linked supramolecular polymers by hierarchical unification of three types of orthogonal noncovalent interactions, including platinum(II)-pyridine coordination-driven self-assembly, zinc-terpyridine complex, and host-guest interactions. The platinum-pyridine coordination provides the primary driving force to form discrete rhomboidal metallacycles. The assembly does not interfere with the zinc-terpyridine complexes, which link the discrete metallacycles into linear supramolecular polymers, and the conjugation length is extended upon the formation of the zinc-terpyridine complexes, which red-shifts the absorption and emission spectra. Finally, host-guest interactions via bis-ammonium salt binding to the benzo-21-crown-7 (B21C7) groups on the platinum acceptors afford the cross-linked supramolecular polymers. By continuous increase of the concentration of the supramolecular polymer to a relatively high level, supramolecular polymer gel is obtained, which exhibits self-healing properties and reversible gel-sol transitions stimulated by various external stimuli, including temperature, K
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